Skip to Content
Merck
All Photos(2)

Key Documents

View All Documentation

345695

Sigma-Aldrich

Titanium(IV) chloride solution

1.0 M in toluene

Synonym(s):

Titanium tetrachloride

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
TiCl4
CAS Number:
7550-45-0
Molecular Weight:
189.68
MDL number:
MFCD00011267
UNSPSC Code:
12352300
PubChem Substance ID:
329755036
NACRES:
NA.55

form

liquid

reaction suitability

reagent type: catalyst
core: titanium

concentration

0.95-1.10 M NaOH (titration)
1.0 M in toluene

density

0.964 g/mL at 25 °C

SMILES string

Cl[Ti](Cl)(Cl)Cl

InChI

1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4

InChI key

XJDNKRIXUMDJCW-UHFFFAOYSA-J

Looking for similar products? Visit Product Comparison Guide

General description

Titanium(IV) chloride participates in the Baylis-Hillman reaction of arylaldehydes with methyl vinyl ketone.[1]

Application

TiCl4 can be used as a precursor for the synthesis of nanosized titaniuim dioxide.[2]

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 2 - Skin Corr. 1B - STOT RE 2 - STOT SE 3

Target Organs

Central nervous system, Respiratory system

Supplementary Hazards

EUH014

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

46.4 °F - closed cup

Flash Point(C)

8 °C - closed cup

Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number
SHBN6714
SHBN3587
SHBH9459
SHBB9156V
74997LJV

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Search for a COA

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Soji Shimizu et al.
Chemical communications (Cambridge, England), 49(16), 1621-1623 (2013-01-23)
Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.
View All Related Papers

Questions

Reviews

No rating value

Active Filters

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service