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329711

Sigma-Aldrich

Zinc dimethyldithiocarbamate

97%

Synonym(s):

Dimethyldithiocarbamic acid zinc salt, Ziram

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About This Item

Linear Formula:
(CH3)2NCSSZnSCSN(CH3)2
CAS Number:
137-30-4
Molecular Weight:
305.82
Beilstein:
3707008
EC Number:
205-288-3
MDL number:
MFCD00064797
UNSPSC Code:
12161600
PubChem Substance ID:
24859808
NACRES:
NA.22

Assay

97%

reaction suitability

core: zinc
reagent type: catalyst

mp

248-257 °C (lit.)

SMILES string

CN(C)C(=S)S[Zn]SC(=S)N(C)C

InChI

1S/2C3H7NS2.Zn/c2*1-4(2)3(5)6;/h2*1-2H3,(H,5,6);/q;;+2/p-2

InChI key

DUBNHZYBDBBJHD-UHFFFAOYSA-L

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Related Categories

Signal Word

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3

Target Organs

Liver,Blood, Respiratory system

Storage Class Code

6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Patch testing with zinc dibenzyldithiocarbamate. A multicentre study of the Information Network of Departments of Dermatology and the German Contact Dermatitis Research Group.
Johannes Geier et al.
Contact dermatitis, 48(4), 209-211 (2003-06-06)
Zisis Vryzas et al.
Journal of agricultural and food chemistry, 50(8), 2220-2226 (2002-04-04)
A simple and rapid method is presented for the analysis of residues of ethylenebis(dithiocarbamate) (maneb, zineb, and mancozeb) and N,N-dimethyldithiocarbamate (thiram and ziram) fungicides in dry tobacco leaves and peaches. Residues are extracted and hydrolyzed to CS(2) in a single
Wim H De Jong et al.
Toxicology, 176(1-2), 123-134 (2002-06-14)
A modified local lymph node assay (LLNA) was used to determine the sensitising activity of four chemicals used for the production of natural rubber latex products. Tetramethylthiuramdisulfide (TMTD), 2-mercaptobenzothiazole (MBT) and zincdimethyldithiocarbamate (ZDMC), three moderate human sensitisers, and diethylamine (DEA)
Thyneice R Taylor et al.
Cell biology and toxicology, 25(5), 447-455 (2008-08-02)
Human natural killer (NK) cells are central in immune defense against tumor and virally infected cells. Ziram is used as an accelerating agent in latex production and as an agricultural fungicide. Previous studies showed that continuous exposure to ziram inhibits
Emanuela Corsini et al.
Toxicology and applied pharmacology, 212(2), 89-98 (2005-08-23)
Mancozeb, a polymeric complex of manganese ethylenebisdithiocarbamate with zinc salt, is widely used in agriculture as fungicide. Literature data indicate that ethylenebisdithiocarbamates (EBDTCs) may have immunomodulatory effects in humans. We have recently found in agricultural workers occupationally exposed to the
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