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244767

Sigma-Aldrich

Lithium tetrafluoroborate

greener alternative

98%

Synonym(s):

Lithium borofluoride, Lithium fluoroborate

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About This Item

Linear Formula:
LiBF4
CAS Number:
14283-07-9
Molecular Weight:
93.75
EC Number:
238-178-9
MDL number:
MFCD00011087
UNSPSC Code:
12352302
PubChem Substance ID:
24854701
NACRES:
NA.23

Assay

98%

form

powder

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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mp

293-300 °C (dec.) (lit.)

greener alternative category

Enabling

SMILES string

[Li+].F[B-](F)(F)F

InChI

1S/BF4.Li/c2-1(3,4)5;/q-1;+1

InChI key

UFXJWFBILHTTET-UHFFFAOYSA-N

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General description

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Application

Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. It is used as a catalyst for mild and efficient aminolysis of oxiranes.Lithium tetrafluoroborate (LiBF4) may be as an additive in electrolyte to improve the performance of Li-ion batteries.

Signal Word

Danger

Hazard Statements

H302,H314,H341

Hazard Classifications

Acute Tox. 4 Oral - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B

Storage Class Code

8B - Non-combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Tetrahedron Letters, 32, 1549-1549 (1991)
Lithium tetrafluoroborate as an electrolyte additive to improve the high voltage performance of lithium-ion battery.
Zuo X, et al.
Journal of the Electrochemical Society, 160(8), A1199-A1204 (2013)
Tetrahedron Letters, 31, 4661-4661 (1990)
Takahiro Ichikawa et al.
Journal of the American Chemical Society, 133(7), 2163-2169 (2011-01-29)
Thermotropic bicontinuous cubic (Cub(bi)) liquid-crystalline (LC) compounds based on a polymerizable ammonium moiety complexed with a lithium salt have been designed to obtain lithium ion-conductive all solid polymeric films having 3D interconnected ionic channels. The monomer shows a Cub(bi) phase
J S Yadav et al.
Carbohydrate research, 332(2), 221-224 (2001-07-04)
The treatment of glycals with allyltrimethylsilane in the presence of lithium tetrafluoroborate in acetonitrile gave the corresponding allyl 2,3-unsaturated C-glycosylic compounds in excellent yields with high anomeric selectivity.
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