Journal of agricultural and food chemistry, 56(12), 4482-4490 (2008-05-23)
The potential role of 2-methyl imidazole in improving lycopene production by Blakeslea trispora with regards to yield, selectivity, and safety aspects was investigated in batch culture. Optimization of the bioprocess conditions in terms of (a) (+) and (-) strain ratio
The X-ray characterization of the five-coordinate picket-fence porphyrin complex, [Co(TpivPP)(2-MeHIm)], is reported. The complex has the displacement of cobalt from the porphyrin plane = 0.15 A, and Co-N(Im) = 2.145(3) and (Co-N(p))(av) = 1.979(3) A. This five-coordinate complex, in the
Angewandte Chemie (International ed. in English), 50(35), 8067-8071 (2011-07-13)
Prenucleation clusters: in situ synchrotron X-ray scattering with a one-second time resolution revealed the occurrence of nano-sized clusters during the nucleation and early growth of nanocrystals of a zeolitic imidazolate framework (ZIF). The complex crystallization process exhibits similarities with crystallization processes
We have found that recombinant human serum albumin (HSA) incorporating tailed porphyrinatoiron(II) in the alpha,alpha,alpha,beta-conformer can reversibly bind and release O2 under physiological conditions (pH 7.3, 37 degrees C) like hemoglobin and myoglobin. beta-2-Methylimidazolyl-tailed porphyrinatoirons (6a, 6b) are synthesized via
Journal of the American Chemical Society, 124(19), 5315-5324 (2002-05-09)
Axial iron ligation and protein encapsulation of the heme cofactor have been investigated as effectors of the reduction potential (E degrees ') of cytochrome c through direct electrochemistry experiments. Our approach was that of partitioning the E degrees ' changes
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