294071
Methoxymethyl phenyl sulfide
97%
Synonym(s):
[(Methoxymethyl)thio]benzene
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About This Item
Linear Formula:
C6H5SCH2OCH3
CAS Number:
Molecular Weight:
154.23
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
Recommended Products
Assay
97%
refractive index
n20/D 1.5632 (lit.)
bp
113-114 °C/18 mmHg (lit.)
density
1.047 g/mL at 25 °C (lit.)
SMILES string
COCSc1ccccc1
InChI
1S/C8H10OS/c1-9-7-10-8-5-3-2-4-6-8/h2-6H,7H2,1H3
InChI key
QPXQVNXSQCRWEV-UHFFFAOYSA-N
General description
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide to methoxymethyl benzenesulfenate has been reported. Methoxymethyl phenyl sulfide undergoes solvent free permanganate oxidation to yield methoxymethyl phenyl sulfone.
Application
Methoxymethyl phenyl sulfide has been used in the preparation of methoxymethyl phenyl sulfoxide.
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
203.0 °F - closed cup
Flash Point(C)
95 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Solvent free permanganate oxidations.
Shaabani A and Lee DG.
Tetrahedron Letters, 42(34), 5833-5836 (2001)
Meisenheimer rearrangement of methoxymethyl phenyl sulfoxide. Formation and disproportionation of methoxymethyl benzenesulfenate.
Maricich TJ and Harrington CK.
Journal of the American Chemical Society, 94(14), 5115-5116 (1972)
S P Hanlon et al.
Microbiology (Reading, England), 144 ( Pt 8), 2247-2253 (1998-08-28)
The enantioselective reduction of racemic sulfoxides by dimethyl sulfoxide reductases from Rhodobacter capsulatus, Escherichia coli, Proteus mirabilis and Proteus vulgaris was investigated. Purified dimethyl sulfoxide reductase from Rhodobacter capsulatus catalysed the selective removal of (S)-methyl p-tolyl sulfoxide from a racemic
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