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41610

Sigma-Aldrich

Dimethyl-sulfat

puriss. p.a., ≥99.0% (GC)

Synonym(e):

Schwefelsäure-dimethylester

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About This Item

Lineare Formel:
(CH3O)2SO2
CAS-Nummer:
77-78-1
Molekulargewicht:
126.13
Beilstein:
635994
EG-Nummer:
201-058-1
MDL-Nummer:
MFCD00008416
UNSPSC-Code:
12352100
PubChem Substanz-ID:
57650074
NACRES:
NA.21

Dampfdichte

4.3 (vs air)

Qualitätsniveau

200

Dampfdruck

0.7 mmHg ( 25 °C)

Qualität

puriss. p.a.

Assay

≥99.0% (GC)

Form

liquid

Selbstzündungstemp.

923 °F

Verunreinigungen

≤0.4% free acid (as H2SO4)

Glührückstand

≤0.02%

Brechungsindex

n20/D 1.386 (lit.)
n20/D 1.387

bp

188 °C (lit.)

mp (Schmelzpunkt)

−32 °C (lit.)

Löslichkeit

ethanol: 0.26 g/mL, clear, colorless
diethyl ether: 1.3 g/5mL, clear, colorless

Dichte

1.333 g/mL at 25 °C (lit.)

Kationenspuren

Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Zn: ≤1 mg/kg

SMILES String

COS(=O)(=O)OC

InChI

1S/C2H6O4S/c1-5-7(3,4)6-2/h1-2H3

InChIKey

VAYGXNSJCAHWJZ-UHFFFAOYSA-N

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Allgemeine Beschreibung

Dimethyl sulfate is the dimethyl ester of sulfuric acid. It undergoes hydrolysis to afford monomethyl sulfate. It is found as contaminant in fly ash and in airborne particulate matter generated during the coal combustion processes.

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Carc. 1B - Eye Dam. 1 - Muta. 2 - Skin Corr. 1B - Skin Sens. 1

Lagerklassenschlüssel

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 3

Flammpunkt (°F)

181.4 °F - closed cup

Flammpunkt (°C)

83 °C - closed cup

Persönliche Schutzausrüstung

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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Analysenzertifikate (COA)

Lot/Batch Number
BCCL0259
BCCH2096
BCCH6719
BCCH7474
BCCH2924

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J D McGhee et al.
Proceedings of the National Academy of Sciences of the United States of America, 76(5), 2133-2137 (1979-05-01)
We have measured the effect of the histones in the nucleosome core particle on methylation of purines in nucleosome DNA by dimethyl sulfate. By using 32P terminally labeled nucleosome cores, we have examined the pattern of strand cleavage at methylated
Kwang Sun Ryu et al.
The journal of physical chemistry. B, 111(4), 731-739 (2007-01-26)
The physical properties of polyaniline (PAn) powder, doped by nucleophilic doping of dimethyl sulfate (DMS), were characterized, as well as its electrochemical behaviors, to investigate the possibility of a power source device adopting the PAn-DMS electrodes. It is shown that
M L Lee et al.
Science (New York, N.Y.), 207(4427), 186-188 (1980-01-11)
Dimethyl sulfate and its hydrolysis product monomethyl sulfate have been found at concentrations as high as 830 parts per million in fly ash and in airborne particulate matter from coal combustion processes. This discovery poses a new environmental problem because
Yogo Sakakibara et al.
Journal of the American Chemical Society, 133(22), 8396-8399 (2011-05-12)
The movement of the small ribosomal subunit (30S) relative to the large ribosomal subunit (50S) during translation is widely known, but many molecular details and roles of rRNA and proteins in this process are still undefined, especially in solution models.
Cecilia E Ström et al.
Nucleic acids research, 39(8), 3166-3175 (2010-12-25)
Base excision repair (BER) represents the most important repair pathway of endogenous DNA lesions. Initially, a base damage is recognized, excised and a DNA single-strand break (SSB) intermediate forms. The SSB is then ligated, a process that employs proteins also
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