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Merck

34352

Mephosfolan

PESTANAL®, analytical standard

Synonym(e):

Diethyl-(4-methyl-1,3-dithiolan-2-yliden)-phosphoramidat

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Über diesen Artikel

Empirische Formel (Hill-System):
C8H16NO3PS2
CAS-Nummer:
Molekulargewicht:
269.32
NACRES:
NA.24
PubChem Substance ID:
UNSPSC Code:
41116107
EC Number:
213-447-3
MDL number:
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grade

analytical standard

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=O)(OCC)\N=C1/SCC(C)S1

InChI

1S/C8H16NO3PS2/c1-4-11-13(10,12-5-2)9-8-14-6-7(3)15-8/h7H,4-6H2,1-3H3/b9-8+

InChI key

LTQSAUHRSCMPLD-CMDGGOBGSA-N

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.
Mephosfolan may be used as an analytical reference standard for the determination of the analyte in tea, grain, fruit- and vegetable-based infant foods and tobacco samples by various chromatography techniques.

Other Notes

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Skull and crossbonesEnvironment

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Oral - Aquatic Chronic 2

Lagerklasse

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Die Dokumentenbibliothek aufrufen

An effective method for pesticide residues determination in tobacco by GC-MS/MS and UHPLC-MS/MS employing acetonitrile extraction with low-temperature precipitation and d-SPE clean-up.
Bernardi G, et al.
Talanta, 161(1), 40-47 (2016)
Applications of LC/ESI-MS/MS and UHPLC/Qq-TOF-MS for the determination of 141 pesticides in tea
Wang J, et al.
Journal of AOAC (Association of Official Analytical Chemists) International, 94(6), 1685-1714 (2011)
N M Bakry et al.
Journal of analytical toxicology, 4(4), 212-214 (1980-07-01)
A sequential thin-layer chromatographic method (STLC) has been developed to analyze the two organophosphorus insecticides phosfolan (O,O-diethyl 1,3-dithiolan-2-ylidenephosphoramidate) and mephospholan (O,O-diethyl 4-methyl-1,3-dithiolan-2-ylidenephosphoramidate) and some of their possible degradation products. Gelman type SA, Instant Thin Layer Chromatography (ITLC) silicic acid-impregnated glass
Determination of 142 pesticides in fruit-and vegetable-based infant foods by liquid chromatography/electrospray ionization-tandem mass spectrometry and estimation of measurement uncertainty.
Wang J and Leung D
Journal of AOAC (Association of Official Analytical Chemists) International, 92(1), 279-301 (2008)
Mararlene Ulberg Pereira et al.
Journal of food science and technology, 57(5), 1719-1730 (2020-04-25)
In this study, a preliminary food quality and safety assessment was performed on organic and cage-free egg samples marketed in the state of Rio de Janeiro, Brazil, that were analyzed concerning veterinary drug and pesticide residues using high performance and

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