31224

Chloramin T Trihydrat

98.0-103.0%, reag. Ph. Eur.

• Synonym(e): N-Chlor-p-toluolsulfonamid Natriumsalz
• Lineare Formel: CH₃C₆H₄SO₂NClNa · 3H₂O
• CAS-Nummer: 7080-50-4
• Molekulargewicht: 281.69
• NACRES: NA.21
• PubChem Substance ID: 57648517
• UNSPSC Code: 12352100
• EC Number: 204-854-7
• MDL number: MFCD00149066
• Beilstein/REAXYS Number: 3924168
• Assay: 98.0-103.0%

Eigenschaften

• Produktname: Chloramin T Trihydrat, reag. Ph. Eur., 98.0-103.0%
• Quality Segment: 100
• agency: USP/NF, reag. Ph. Eur.
• assay: 98.0-103.0%
• impurities: ≤1.5% insoluble in ethanol
• pH: 8-10 (20 °C, 5%)
• mp: 167-170 °C (lit.)
• SMILES string: O.O.O.Cc1ccc(cc1)S(=O)(=O)N([Na])Cl
• InChI: 1S/C7H7ClNO2S.Na.3H2O/c1-6-2-4-7(5-3-6)12(10,11)9-8;;;;/h2-5H,1H3;;3*1H2/q-1;+1;;;
• InChI key: NZYOAGBNMCVQIV-UHFFFAOYSA-N

Beschreibung

General description

Chloramine-T trihydrate is a widely used oxidizing agent in organic synthesis. It acts as a source of halonium cation and nitrogen anion and thus acts as a base and nucleophile. Due to its reactivity with a wide range of functional groups, it is involved in different molecular transformations. It is effective in acidic, neutral, and basic conditions.

Application

Chloramine-T trihydrate can be used as:

• A reagent for chlorination in drinking water treatment.
• A dehydrogenating agent for the oxidative dehydrogenation of aromatic aldehyde phenylhydrazones to synthesize nitrile imines.
• The nitrene source for the aziridination of alkenes and the amidation of cyclic ethers.

Sicherheitshinweise

• pictograms: GHS08,GHS05,GHS07
• signalword: Danger
• hcodes: H302,H314,H334
• pcodes: P260 - P280 - P301 + P312 - P303 + P361 + P353 - P304 + P340 + P310 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B
• supp_hazards: EUH031
• Lagerklasse: 8A - Combustible corrosive hazardous materials
• wgk: WGK 2
• flash_point_f: 377.6 °F - closed cup
• flash_point_c: 192 °C - closed cup
• ppe: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges