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207942

Hydrazin Monohydrat

N2H4 64-65 %, reagent grade, ≥97%

Synonym(e):

Hydraziniumhydroxid

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Lineare Formel:
NH2NH2 · H2O
CAS-Nummer:
Molekulargewicht:
50.06
UNSPSC Code:
12352300
NACRES:
NA.21
PubChem Substance ID:
EC Number:
206-114-9
Beilstein/REAXYS Number:
878137
MDL number:
Assay:
≥97%
Grade:
reagent grade
Form:
liquid
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Unterstützung erhalten


grade

reagent grade

Quality Segment

vapor density

>1 (vs air)

vapor pressure

5 mmHg ( 25 °C)

assay

≥97%

form

liquid

composition

N2H4, 64-65%

expl. lim.

99.99 %

refractive index

n20/D 1.428 (lit.)

pH

10.6-10.7 (10 g/L)

bp

120.1 °C (lit.)

mp

−51.7 °C (lit.)

density

1.032 g/mL at 25 °C (lit.)

SMILES string

O.NN

InChI

1S/H4N2.H2O/c1-2;/h1-2H2;1H2

InChI key

IKDUDTNKRLTJSI-UHFFFAOYSA-N

General description

Hydrazin-Monohydrat-Kristalle weisen ein triklinisches Kristallsystem und die Raumgruppe P3121 auf.

Application

Hydrazin-Monohydrat wird für die Synthese von 2-(6-Ethylamino-3-ethylimino-2,7-dimethyl-3H-xanthen-9-yl)benzoesäurehydrazid[1] und Vinylbenzylamin-Hydrochlorid verwendet. Durch Zersetzung in Gegenwart eines unterstützten, aus Ni-Pt-legierten Nanopartikeln und einem mesoporösen CeO2-Träger bestehenden bimetallischen Katalysators kann es auch als Wasserstoffquelle eingesetzt werden.[2]
Hydrazin-Monohydrat kann als Reduktionsmittel für folgende Reduktionen verwendet werden:
  • Nitroarene in Gegenwart von Wasserstoffperoxid-funktionalisierten Kohlenstoffnanoröhrchen.
  • 4-Iod-3-nitroanisol zur Bildung von 2-Iod-5-methoxyanilin.
  • Graphenoxid (GO) zur Bildung von Graphen.

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Dieser Artikel
53847492787225819
form

liquid

form

liquid

form

liquid

form

liquid

assay

≥97%

assay

-

assay

-

assay

-

Quality Level

100

Quality Level

200

Quality Level

200

Quality Level

200

grade

reagent grade

grade

-

grade

-

grade

reagent grade

mp

−51.7 °C (lit.)

mp

-

mp

−51.7 °C (lit.)

mp

-

density

1.032 g/mL at 25 °C (lit.)

density

1.01 g/mL at 20 °C

density

1.073 g/mL at 25 °C

density

1.029 g/mL at 25 °C (lit.)


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signalword

Danger

Lagerklasse

3 - Flammable liquids

flash_point_f

100.4 °F - closed cup - (anhydrous substance)

flash_point_c

38 °C - closed cup - (anhydrous substance)

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - Skin Sens. 1


Zulassungslistungen

Zulassungslistungen werden hauptsächlich für chemische Produkte erstellt. Für nicht-chemische Produkte können hier nur begrenzte Angaben gemacht werden. Kein Eintrag bedeutet, dass keine der Komponenten gelistet ist. Es liegt in der Verantwortung des Benutzers, die sichere und legale Verwendung des Produkts zu gewährleisten.

7803-57-8

CAS No.

7803-57-8

CAS No.


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Analysenzertifikate (COA)

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Questions

1–4 of 4 Questions  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/418/501/product-dating-information-06-25-mk.pdf

      Helpful?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Helpful?

  3. Hi, is this a salt or solution?

    1 answer
    1. This product is a monohydrate and is a liquid at room temperature with a density of 1.032 g/mL. The material is 64 - 65% Hydrazine with the remainder being water. This material is not a salt form.

      Helpful?

  4. Is there a shelf life for this product and if so how long will it last?

    1 answer
    1. This product is not assigned an expiration date or recommended retest date. Products with no expiration date or recommended retest date should be routinely inspected by customers to ensure they perform as expected. These products are also subject to a one year warranty from the date of shipment. For more information you may access the "Product Dating Information" document under "ADDITIONAL USEFUL DOCUMENTS ABOUT OUR PRODUCTS" at the bottom of the Quality Services page with this link: https://www.sigmaaldrich.com/life-science/quality-and-regulatory-management/quality-services.

      Helpful?

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