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Merck

E50604

Sigma-Aldrich

Ethyltriphenylphosphonium

99%

Synonym(e):

TEP

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About This Item

Lineare Formel:
[(C6H5)3P+C2H5]Br-
CAS-Nummer:
Molekulargewicht:
371.25
Beilstein:
3599630
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352002
PubChem Substanz-ID:
NACRES:
NA.22

Assay

99%

Eignung der Reaktion

reaction type: C-C Bond Formation

mp (Schmelzpunkt)

203-205 °C (lit.)

SMILES String

[Br-].CC[P+](c1ccccc1)(c2ccccc2)c3ccccc3

InChI

1S/C20H20P.BrH/c1-2-21(18-12-6-3-7-13-18,19-14-8-4-9-15-19)20-16-10-5-11-17-20;/h3-17H,2H2,1H3;1H/q+1;/p-1

InChIKey

JHYNXXDQQHTCHJ-UHFFFAOYSA-M

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Anwendung

Reactant for synthesis of:
  • D-amino acids from L-cysteine-derived thiazolidines
  • Leiodolide A via aldol reactions and Horner-Wadsworth-Emmons olefination
  • Cycloalkanoindolines via diastereoselective intramolecular inimo-ene reactions
  • WXYZA′ domain of maitotoxin using the coupling of key building blocks

Reactant for:
  • Solid-state metathesis polycondensation to form alkyl-dipropenylthiophene monomers
  • Mizoroki-Heck cyclization and cascading Tsuji-Trost cyclization / lactonization cyclization reactions for synthesis of an ABC ring system

Piktogramme

Skull and crossbonesCorrosion

Signalwort

Danger

Gefahreneinstufungen

Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1

Lagerklassenschlüssel

6.1D - Non-combustible acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

WGK

WGK 2

Flammpunkt (°F)

401.0 °F

Flammpunkt (°C)

205 °C

Persönliche Schutzausrüstung

dust mask type N95 (US), Eyeshields, Faceshields, Gloves


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