901243

4-(Acetylamino)phenyl]imidodisulfuryl difluoride

≥98%

• Synonym(e): (4-Acetamidophenyl)(fluorosulfonyl)sulfamoyl fluoride, AISF
• Empirische Formel (Hill-System): C₈H₈F₂N₂O₅S₂
• CAS-Nummer: 2172794-56-6
• Molekulargewicht: 314.29
• MDL number: MFCD31625434
• UNSPSC Code: 12352101
• NACRES: NA.22
• Assay: ≥98%
• Form: powder or crystals

Eigenschaften

• Quality Segment: 100
• assay: ≥98%
• form: powder or crystals
• reaction suitability: reaction type: Halogenations
• mp: 146-149 °C
• functional group: amide
• SMILES string: F[S](=O)(=O)N([S](=O)(=O)F)c1ccc(cc1)NC(=O)C
• InChI key: SMMIWAIOWMUFCR-UHFFFAOYSA-N

Beschreibung

Application

4-(Acetylamino)phenyl]imidodisulfuryl difluoride (AISF) is a shelf-stable, crystalline reagent for synthesis of fluorosulfates and sulfamoyl fluorides via reaction with phenol and amine nucleophiles. A convenient alternative to the toxic sulfuryl fluoride gas traditionally required for installation of the valuable -SO₂F functional group, the solid reagent AISF will find wide utility in preparation of synthetic precursors as well as chemical biology, polymer chemistry, cross-coupling, and deoxyfluorination applications.

Other Notes

Introduction of a Crystalline, Shelf-Stable Reagent for the Synthesis of Sulfur(VI) Fluorides

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Sicherheitshinweise

• Lagerklasse: 11 - Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable