78055

L-Phenylalaninallylester -p-toluolsulfonat (Salz)

• Empirische Formel (Hill-System): C₁₂H₁₅NO₂ · C₇H₈O₃S
• CAS-Nummer: 88224-00-4
• Molekulargewicht: 377.45
• PubChem Substance ID: 57652718
• UNSPSC Code: 12352200
• Beilstein/REAXYS Number: 5212778
• MDL number: MFCD00043306

Eigenschaften

• optical activity: [α]20/D +10.5±1°, c = 1% in DMF
• mp: 155-158 °C
• application(s): peptide synthesis
• SMILES string: Cc1ccc(cc1)S(O)(=O)=O.N[C@@H](Cc2ccccc2)C(=O)OCC=C
• InChI: 1S/C12H15NO2.C7H8O3S/c1-2-8-15-12(14)11(13)9-10-6-4-3-5-7-10;1-6-2-4-7(5-3-6)11(8,9)10/h2-7,11H,1,8-9,13H2;2-5H,1H3,(H,8,9,10)/t11-;/m0./s1
• InChI key: PKXPRZFLCJFMHN-MERQFXBCSA-N

Beschreibung

Other Notes

Used in peptide and N-glycopeptide synthesis; the ester is selectively deblocked with (Ph₃P)₃RhCl