735809

[2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridin]carbonylchlorhydridoruthenium(II)

powder

• Synonym(e): Milstein Catalyst Precursor, [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine]ruthenium(II) chlorocarbonyl hydride
• Empirische Formel (Hill-System): C₂₀H₃₆ClN₂OPRu
• CAS-Nummer: 863971-62-4
• Molekulargewicht: 488.01
• UNSPSC Code: 12352300
• PubChem Substance ID: 329765059
• NACRES: NA.22
• MDL number: MFCD16038117

Eigenschaften

• Produktname: [2-(Di-tert-butylphosphinomethyl)-6-(diethylaminomethyl)pyridin]carbonylchlorhydridoruthenium(II),
• form: powder
• reaction suitability: core: ruthenium, reagent type: catalyst
• greener alternative product characteristics: Catalysis; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product, Sustainability features
• greener alternative category: ,
• SMILES string: Cl[RuH].[C-]#[O+].CCN(CC)Cc1cccc(CP(C(C)(C)C)C(C)(C)C)n1
• InChI: 1S/C19H35N2P.CO.ClH.Ru.H/c1-9-21(10-2)14-16-12-11-13-17(20-16)15-22(18(3,4)5)19(6,7)8;1-2;;;/h11-13H,9-10,14-15H2,1-8H3;;1H;;/q;;;+1;/p-1
• InChI key: RZCAJPSOQUIHSH-UHFFFAOYSA-M

Beschreibung

General description

May contain up to 10% acetone and/or THF.

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Precursor to active Ru catalyst for the dehydrogenative coupling of amines and alcohols to form amide bonds.

Precursor to active ruthenium catalyst for greener amide bond formation by dehydrogenative coupling of amines and alcohols.

Direct Synthesis of Amides from Alcohols and Amines with Liberation of H2

Sicherheitshinweise

• Piktogramme: GHS08,GHS07
• Signalwort: Warning
• Gefahrencodes: H319,H351
• Sicherheitshinweise: P281 - P305 + P351 + P338
• Hazard Classifications: Carc. 2 - Eye Irrit. 2
• supp_hazards: EUH019
• Lagerklasse: 13 - Non Combustible Solids
• Was ist los?: WGK 3
• Flammpunkt (°F): Not applicable
• Flammpunkt (°C): Not applicable