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638080
2-Di-tert-butylphosphin-2′,4′,6′-triisopropylbiphenyl
98%, solid
Nachhaltigkeitsmerkmale
Synonym(e):
tert.-Butyl-XPhos
Größe auswählen
| Größe/SKU | Verfügbarkeit | Preis |
|---|---|---|
1 g | Warenkorb auf Verfügbarkeit prüfen | € 59,40 |
5 g | Warenkorb auf Verfügbarkeit prüfen | € 191,00 |
25 g | Warenkorb auf Verfügbarkeit prüfen | € 905,00 |
100 g | Warenkorb auf Verfügbarkeit prüfen | € 1.650,00 |
500 g | Versand innerhalb von 5 Werktagen. (Bei Bestellungen außerhalb der USA rechnen Sie bitte zusätzlich 1-2 Wochen für die Lieferung ein) | € 7.610,00 |
Über diesen Artikel
Produktname
2-Di-tert-butylphosphin-2′,4′,6′-triisopropylbiphenyl, 98%
Quality Segment
product line
Buchwald Ligand
assay
98%
form
solid
reaction suitability
reaction type: Cross Couplings, reagent type: ligand
reaction type: Arylations, reagent type: ligand
reaction type: Buchwald-Hartwig Cross Coupling Reaction, reagent type: ligand
reaction type: Carboxylations, reagent type: ligand
reaction type: Decarboxylations
greener alternative product score
old score: 12
new score: 1
Find out more about DOZN™ Scoring
greener alternative product characteristics
Atom Economy
Design for Energy Efficiency
Use of Renewable Feedstocks
Learn more about the Principles of Green Chemistry.
sustainability
Sustainability features
mp
148-151 °C (lit.)
functional group
phosphine
SMILES string
CC(P(C(C=CC=C1)=C1C(C(C(C)C)=CC(C(C)C)=C2)=C2C(C)C)C(C)(C)C)(C)C
InChI
1S/C29H45P/c1-19(2)22-17-24(20(3)4)27(25(18-22)21(5)6)23-15-13-14-16-26(23)30(28(7,8)9)29(10,11)12/h13-21H,1-12H3
InChI key
SACNIGZYDTUHKB-UHFFFAOYSA-N
General description
Learn more about Buchwald Phosphine Ligands
Application
It can be used in the following reactions:
- Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
- Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
- Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.
Legal Information
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Dieser Artikel | |||
|---|---|---|---|
| description 98% | description 95% | description - | description ≥98%, ISOM8™ |
| assay 98% | assay 95% | assay - | assay ≥98% |
| reaction suitability reagent type: ligand | reaction suitability reaction type: Sonogashira Coupling, reaction type: Negishi Coupling, reaction type: Stille Coupling, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Hiyama Coupling, reaction type: Suzuki-Miyaura Coupling, reagent type: catalyst | reaction suitability reagent type: ligand | reaction suitability reaction type: Arylations, reaction type: Carboxylations, reaction type: Decarboxylations, reagent type: ligand, reaction type: Buchwald-Hartwig Cross Coupling Reaction, reaction type: Cross Couplings |
| form solid | form powder or crystals | form solid | form solid |
| functional group phosphine | functional group phosphine | functional group - | functional group phosphine |
| Quality Level 300 | Quality Level - | Quality Level 100 | Quality Level 300 |
| mp 148-151 °C (lit.) | mp 148-151 °C (lit.), 150 °C | mp - | mp 148-151 °C (lit.), 144-145 °C (Lit.) |
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Lagerklasse
11 - Combustible Solids
Was ist los?
WGK 3
Flammpunkt (°F)
Not applicable
Flammpunkt (°C)
Not applicable
PSA (Persönliche Schutzausrüstung)
Eyeshields, Gloves, type N95 (US)
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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