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Merck

52270

Sigma-Aldrich

1-Hexadecanthiol

≥95.0% (GC)

Synonym(e):

Cetylmercaptan, Hexadecylmercaptan, Mercaptan C16

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About This Item

Lineare Formel:
CH3(CH2)15SH
CAS-Nummer:
Molekulargewicht:
258.51
Beilstein:
1748495
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

Assay

≥95.0% (GC)

Brechungsindex

n20/D 1.462 (lit.)
n20/D 1.464

bp

184-191 °C/7 mmHg (lit.)

mp (Schmelzpunkt)

18-20 °C (lit.)

Übergangstemp.

solidification point 15-18 °C(lit.)

Dichte

0.84 g/mL at 25 °C (lit.)

SMILES String

CCCCCCCCCCCCCCCCS

InChI

1S/C16H34S/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15-16-17/h17H,2-16H2,1H3

InChIKey

ORTRWBYBJVGVQC-UHFFFAOYSA-N

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Allgemeine Beschreibung

1-Hexadecanethiol (HDT) readily forms self-assembled monolayer (SAMs) on gold surfaces. Phase separation characteristics of binary SAMs [made up of HDT and 3-mercaptopropionic acid] on the surface of Au(111) have been investigated. Interaction between gold surface and SAM of HDT has been investigated by atomic force microscopy (AFM).

Anwendung

1-Hexadecanethiol has been used in the preparation of cholesterol-PIE12-trimer and alkyl-PIE12-trimer (PIE12-trimer = protease-resistant trimeric D-peptide inhibitor). It may be used for the functionalization of silver nanowires.

Lagerklassenschlüssel

10 - Combustible liquids

WGK

WGK 3

Flammpunkt (°F)

215.6 °F - closed cup

Flammpunkt (°C)

102 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


Analysenzertifikate (COA)

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Die Dokumentenbibliothek aufrufen

X Torrelles et al.
Langmuir : the ACS journal of surfaces and colloids, 20(21), 9396-9402 (2004-10-06)
The c(4 x 2) structure of C16H33SH alkanethiol monolayers self-assembled on Au(111) has been studied by grazing incidence X-ray diffraction. This structure coexists on the surface with the (radical3x radical3)R30 degrees phase. The structural refinement of the c(4 x 2)
Jialin Wang et al.
Langmuir : the ACS journal of surfaces and colloids, 24(15), 7889-7896 (2008-06-26)
An atomic force microscope (AFM) was used to measure the forces between gold surfaces with and without hydrophobizing them by the self-assembly of 1-hexadecanethiol. The forces measured between bare gold surfaces were fitted to the Derjaguin-Landau-Verwey-Overbeek (DLVO) theory with a
Dana M Rosu et al.
Langmuir : the ACS journal of surfaces and colloids, 25(2), 919-923 (2008-12-25)
Infrared spectroscopic ellipsometry was used for determination of molecular orientation and for lateral homogeneity studies of organic monolayers on GaAs and Au, the organic layer being either octanedithiol or hexadecanethiol (HDT). The laterally resolved measurements were performed with the infrared
Lower hole-injection barrier between pentacene and a 1-hexadecanethiol-modified gold substrate with a lowered work function.
Hong K, et al.
Organic Electronics, 9(1), 21-29 (2008)
Langmuir-Blodgett silver nanowire monolayers for molecular sensing using surface-enhanced Raman spectroscopy.
Tao A, et al.
Nano Letters, 3(9), 1229-1233 (2003)

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