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Merck

240761

Sigma-Aldrich

1-Hexen

≥99%

Synonym(e):

1-n-Hexene

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100 ML
€ 38,80

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50 ML
€ 28,40
100 ML
€ 38,80

About This Item

Lineare Formel:
CH3(CH2)3CH=CH2
CAS-Nummer:
Molekulargewicht:
84.16
Beilstein:
1209240
EG-Nummer:
MDL-Nummer:
UNSPSC-Code:
12352100
PubChem Substanz-ID:
NACRES:
NA.22

€ 28,40


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Dampfdichte

3 (vs air)

Qualitätsniveau

Dampfdruck

155 mmHg ( 21.1 °C)

Assay

≥99%

Form

liquid

Selbstzündungstemp.

487 °F

Brechungsindex

n20/D 1.388 (lit.)

bp

60-66 °C (lit.)

Dichte

0.678 g/mL at 25 °C (lit.)

Funktionelle Gruppe

allyl

SMILES String

CCCCC=C

InChI

1S/C6H12/c1-3-5-6-4-2/h3H,1,4-6H2,2H3

InChIKey

LIKMAJRDDDTEIG-UHFFFAOYSA-N

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Allgemeine Beschreibung

The kinetics of polymerization of 1-hexene was studied using a family of five zirconium amine bis-phenolate catalysts[1]. Polymerization reaction of 1-hexene catalyzed by a series of hafnium complexes was studied[2].

Anwendung

  • 1-Hexene in High Molecular Weight Polymer Synthesis: The synthesis of high molecular weight copolymers from 1-hexene and methyl acrylate using Lewis acid catalysts showcased advanced applications in materials science, specifically in developing durable and versatile polymer materials (Wan et al., 2024).
  • 1-Hexene′s Role in Proton-Exchange Membrane Enhancement: Utilizing 1-hexene in the structural characterization and enhancement of physicochemical properties of functionally porous proton-exchange membranes highlights its critical role in improving energy efficiency and performance in fuel cell technologies (Ponomar et al., 2024).

Piktogramme

FlameHealth hazard

Signalwort

Danger

H-Sätze

Gefahreneinstufungen

Asp. Tox. 1 - Flam. Liq. 2

Zusätzliche Gefahrenhinweise

Lagerklassenschlüssel

3 - Flammable liquids

WGK

WGK 2

Flammpunkt (°F)

-13.0 °F - closed cup

Flammpunkt (°C)

-25.0 °C - closed cup

Persönliche Schutzausrüstung

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Die Dokumentenbibliothek aufrufen

D Keith Steelman et al.
Journal of the American Chemical Society, 135(16), 6280-6288 (2013-03-23)
The kinetics of 1-hexene polymerization using a family of five zirconium amine bis-phenolate catalysts, Zr[tBu-ON(X)O]Bn2 (where X = THF (1), pyridine (2), NMe2 (3), furan (4), and SMe (5)), has been investigated to uncover the mechanistic effect of varying the
Takahiro Yasumoto et al.
Dalton transactions (Cambridge, England : 2003), 42(25), 9120-9128 (2012-12-14)
Non-bridged half-metallocene dimethyl complexes of group 4 metals 2a-4a with an N-4-methoxyphenyl(iminomethyl)pyrrolyl ligand 1a were synthesized and characterized by NMR spectroscopy and X-ray analysis. Upon activation with [Ph3C][B(C6F5)4], these complexes became active catalysts for the polymerization of 1-hexene. A series
Lingyan Gong et al.
Journal of colloid and interface science, 569, 219-228 (2020-03-01)
The current mechanism of surfactant enhanced oil recovery (EOR) mainly relies on forming middle-phase microemulsions to get ultra-low oil-water interfacial tension. However, residual oil can also be recovered using low concentration surfactant solutions without microemulsion formation, and the interaction between
Chia-Hsiu Chen et al.
Journal of the American Chemical Society, 137(21), 6965-6971 (2015-05-12)
The stereochemistry, kinetics, and mechanism of olefin polymerization catalyzed by a set of zirconium-based metallocenes was studied by NMR using dissolution dynamic nuclear polarization (DNP). Hyperpolarized 1-hexene was polymerized in situ with a C2 symmetric catalyst, [(EBI)ZrMe][B(C6F5)4] (EBI = rac-(C2H4(1-indenyl)2))
Yuichi Ito et al.
Implant dentistry, 24(4), 477-479 (2015-06-04)
The evaluation of bone quality at the site of the alveolar bone for a dental implant is very important. This study presents an easy technique for direct evaluation of alveolar bone quality using nondecalcified cryofilm frozen sections on human alveolar

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    1 answer
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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