CRM72861

Captafol

certified reference material, TraceCERT^®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

• Empirical Formula (Hill Notation): C₁₀H₉Cl₄NO₂S
• CAS Number: 2425-06-1
• Molecular Weight: 349.06
• MDL number: MFCD00041816
• UNSPSC Code: 41116107
• NACRES: NA.24

Properties

• grade: certified reference material; TraceCERT^®
• Quality Level: 300
• product line: TraceCERT^®
• shelf life: limited shelf life, expiry date on the label
• manufacturer/tradename: Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
• format: neat
• SMILES string: ClC(Cl)C(Cl)(Cl)SN1C(=O)C2CC=CCC2C1=O
• InChI: 1S/C10H9Cl4NO2S/c11-9(12)10(13,14)18-15-7(16)5-3-1-2-4-6(5)8(15)17/h1-2,5-6,9H,3-4H2
• InChI key: JHRWWRDRBPCWTF-UHFFFAOYSA-N

Description

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com

Captafol is a phthalimide fungicide, used for its non-systemic protective and curative benefits on various fruits and vegetables such as pome fruit, stone fruit, potatoes, carrots, apples, tomatoes, beets, cotton, peanuts, and rice.
As per Regulation (EC) No. 1107/2009, repealing directive 91/414/EEC, captafol is not approved for use in the European Union as a plant protection product. But maximum residue levels of 0.02 mg/kg and 0.05 mg/kg are allowed for its presence in frozen/fresh fruits and tree nuts respectively according to the EU Reg. No 899/2012.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
Captafol CRM can also be used as follows:

• Development and validation of a method for simultaneous detection and quantification of captan, captafol, folpet, iprodione, and their main metabolites in six samples of fruits and vegetables by liquid chromatography-tandem mass spectrometry (LC-MS/MS)
• Multi-residue analysis of captan, captafol, folpet, and iprodione, along with their major degradation products in cereal samples of rice, wheat, sorghum, and corn by dispersive solid-phase extraction (d-SPE) and liquid chromatography-tandem mass spectrometry (LC-MS/MS)
• Simultaneous determination of 407 pesticide residues in organic tea sample by UPLC-MS/MS and GC-MS/MS after a QuEChERS-based sample extraction
• Multi-class analysis of 119 pesticide residues in fish samples by gas chromatography-quadrupole time of flight-mass spectrometry (GC-QTOF-MS)
• Validation of a method for multi-residue analysis of 150 pesticides in yam, taro, and sweet potato samples involving pressurized liquid extraction (PLE) followed by GC-MS/MS determination
• Liquid-liquid extraction and enhanced matrix removal-lipid (EMR-Lipid) cartridge clean-up of 46 pesticide residues from edible oil samples, followed by their gas chromatography-tandem mass spectrometry (GC-MS/MS) determination

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Safety Information

• Pictograms: GHS08,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H317,H350,H410
• Precautionary Statements: P201 - P202 - P273 - P280 - P302 + P352 - P308 + P313
• Hazard Classifications: Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B - Skin Sens. 1
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable