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About This Item
Empirical Formula (Hill Notation):
C14F24
CAS Number:
Molecular Weight:
624.11
Beilstein:
2514226
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NB.61
Pricing and availability is not currently available.
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grade
for ion-selective electrodes
Quality Level
description
solvent for preparation of membranes
product line
Selectophore™
bp
212-218 °C
density
2.03 g/mL at 20 °C
SMILES string
FC1(F)C(F)(F)C(F)(F)C2(F)C(F)(C1(F)F)C(F)(F)C(F)(F)C3(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C23F
InChI
1S/C14F24/c15-1-2(16)4(18,10(29,30)14(37,38)12(33,34)6(2,21)22)8(25,26)7(23,24)3(1,17)9(27,28)13(35,36)11(31,32)5(1,19)20
InChI key
QKENRHXGDUPTEM-UHFFFAOYSA-N
Related Categories
General description
Visit our Sensor Applications portal to learn more.
Application
Perfluoroperhydrophenanthrene finds application as an intraoperative and postoperative surgical adjunct tool, during retinal operations and study.[1][2]
Solvent for fluorous liquid phase in ion-selective electrodes
Legal Information
Selectophore is a trademark of Merck KGaA, Darmstadt, Germany
Storage Class Code
10 - Combustible liquids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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C Batman et al.
Ophthalmic surgery and lasers, 29(2), 144-146 (1998-03-21)
Perfluorocarbon liquids have gained wide acceptance as intraoperative tools that can simplify vitreoretinal surgical maneuvers. These low-viscosity liquids facilitate injection into the eye and removal from the eye during surgery. Tolerance to perfluoroperhydrophenanthrene and the development of proliferative vitreoretinopathy with
U Stolba et al.
Retina (Philadelphia, Pa.), 17(2), 146-153 (1997-01-01)
Anterior and posterior segment changes of experimental vitreous and aqueous substitution with Perfluorophenanthrene were evaluated. In 28 rabbit eyes that underwent vitrectomy, tamponades of 1.2 cc Perfluorophenanthrene remained as long as 8 weeks under clinical and electrophysiologic control. Histologic examinations
Paul G Boswell et al.
Journal of the American Chemical Society, 127(25), 8958-8959 (2005-06-23)
Potentiometric sensors based on fluorous membranes doped with a fluorophilic tetraphenylborate derivative are shown to have a remarkably wide range of selectivities that exceeds the selectivity range of conventional polymeric membranes by 8 orders of magnitude. The fluorous character of
Paul G Boswell et al.
Journal of the American Chemical Society, 127(48), 16976-16984 (2005-12-01)
Despite the widespread use of perfluorinated solvents with amino and ether groups in a variety of application fields, the coordinative properties of these compounds are poorly known. It is generally assumed that the electron withdrawing perfluorinated moieties render these functional
Chun-Ze Lai et al.
Analytical chemistry, 82(18), 7634-7640 (2010-08-31)
Ionophore-doped sensing membranes exhibit greater selectivities and wider measuring ranges if their membrane matrixes are noncoordinating and solvate interfering ions poorly. This is particularly true for fluorous phases, which are the least polar and polarizable condensed phases known. In this
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