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802425

Sigma-Aldrich

2-Bromo-1,10-phenanthroline

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About This Item

Empirical Formula (Hill Notation):
C12H7BrN2
CAS Number:
Molecular Weight:
259.10
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22

form

powder

Quality Level

mp

160-165 °C

SMILES string

BrC1=NC2=C(N=CC=C3)C3=CC=C2C=C1

InChI

1S/C12H7BrN2/c13-10-6-5-9-4-3-8-2-1-7-14-11(8)12(9)15-10/h1-7H

InChI key

ZRJUDAZGVGIDLP-UHFFFAOYSA-N

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Application

Brominated phenanthroline can be synthesized via a method reported by Baran and coworkers using a two-step protocol through N-Oxide formation using m-CBPA (Aldrich 273031) and bromination using TBAB (Sigma-Aldrich 426288) and p-Toluenesulfonic anhydride (Aldrich 259764).

Signal Word

Danger

Hazard Statements

Hazard Classifications

Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Storage Class Code

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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