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119342

Sigma-Aldrich

(Dimethylaminomethyl)ferrocene

≥95%

Synonym(s):

(Ferrocenylmethyl)dimethylamine, Ferrocenemethylamine, N,N-Dimethylferrocenylmethylamine

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About This Item

Empirical Formula (Hill Notation):
C13H17FeN
CAS Number:
Molecular Weight:
243.13
EC Number:
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

Quality Level

Assay

≥95%

reaction suitability

core: iron
reagent type: catalyst

refractive index

n20/D 1.59 (lit.)

bp

124-128 °C/2.5 mmHg (lit.)

density

1.228 g/mL at 25 °C (lit.)

storage temp.

2-8°C

SMILES string

[Fe].[CH]1[CH][CH][CH][CH]1.CN(C)C[C]2[CH][CH][CH][CH]2

InChI

1S/C8H12N.C5H5.Fe/c1-9(2)7-8-5-3-4-6-8;1-2-4-5-3-1;/h3-6H,7H2,1-2H3;1-5H;

InChI key

JJJSTEANRWLZBH-UHFFFAOYSA-N

General description

(Dimethylaminomethyl) ferrocene (DMAMF) is a ferrocene with a dimethylaminomethyl substituent attached to one of the cyclopentadienyl ligands. It can be used as a precursor in the preparation of iron oxide-based films.

Application

(Dimethylaminomethyl)ferrocene can be used as:
  • A Precursor in the preparation of iron oxide and magnesium-doped iron oxide films by atomic layer deposition (ALD).
  • An amine ligand in the synthesis of pentacarbonyl{[(dimethylamino)methyl]ferrocene}tungsten complex.

Storage Class Code

10 - Combustible liquids

WGK

WGK 3

Flash Point(F)

235.4 °F - closed cup

Flash Point(C)

113 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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[(Dimethylamino)methyl] ferrocene as an Amine Ligand: Study of the Bonding and X-Ray Crystal and Molecular Structure of the Pentacarbonyl{[(dimethylamino)methyl] ferrocene}tungsten Complex
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Reactivity of horseradish peroxidase compounds I and II (HRP-I and HRP-II) toward organometallicic substrates, viz water-soluble ferrocenes RFc (R = COOH and CH2NMe2), has been studied at 25 degrees C, pH 6.0 and ionic strength 0.1 M. The second-order rate
Directly fused highly substituted naphthalenes via Pd-catalyzed dehydrogenative annulation of N, N-dimethylaminomethyl ferrocene using a redox process with a substrate
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Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 20(8), 1143-1146 (2004-09-09)
We propose an electron transfer-mediated amperometric enzyme biosensor based on plasma-polymerized thin film of dimethylaminomethylferrocene (DMAMF) on a sputtered gold electrode. The DMAMF plasma-polymerized film is deposited directly onto the surface of the electrode under dry conditions. The resulting thin

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