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Merck

PS1016

Acifluorfen

analytical standard

Sinónimos:

5-(2-Chloro-α,α,α-trifluoro-p-tolyloxy)-2-nitrobenzoic acid, 5-[2-Chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoic acid

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About This Item

Fórmula empírica (notación de Hill):
C14H7ClF3NO5
Número de CAS:
Peso molecular:
361.66
Beilstein/REAXYS Number:
2953865
EC Number:
MDL number:
UNSPSC Code:
41116107
PubChem Substance ID:

grade

analytical standard

packaging

ampule of 250 mg

manufacturer/tradename

Chem Service, Inc. PS-1016

application(s)

agriculture
environmental

SMILES string

OC(=O)c1cc(Oc2ccc(cc2Cl)C(F)(F)F)ccc1[N+]([O-])=O

InChI

1S/C14H7ClF3NO5/c15-10-5-7(14(16,17)18)1-4-12(10)24-8-2-3-11(19(22)23)9(6-8)13(20)21/h1-6H,(H,20,21)

InChI key

NUFNQYOELLVIPL-UHFFFAOYSA-N

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General description

Acifluorfen is a photobleaching herbicide, used as selective preemergence and postemergence weed control in soybean, peanuts and legumes. It causes the photooxidative destruction of pigments and lipids in sensitive plant species.

Application

Acifluorfen may be used as a reference standard for the determination of aclonifen herbicide in water samples using high-performance liquid chromatography coupled with diode array tandem mass spectrometric detection.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Skin Irrit. 2

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


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Certificados de análisis (COA)

Lot/Batch Number

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Acifluorfen effects on intermediates of chlorophyll synthesis in green cucumber cotyledon tissues.
Becerril J, et al.
Pesticide Biochemistry and Physiology, 35(2), 119-126 (1989)
Effects of acifluorfen on endogenous antioxidants and protective enzymes in cucumber (Cucumis sativus L.) cotyledons.
Kenyon W H, et al.
Plant Physiology, 79(3), 862-866 (1985)
Determination of diphenyl-ether herbicides and metabolites in natural waters using high-performance liquid chromatography with diode array tandem mass spectrometric detection.
Lagana A, et al.
Analytica Chimica Acta, 414(1-2), 79-94 (2000)
Lu Sun et al.
Amino acids, 37(3), 523-530 (2009-03-07)
Protoporphyrinogen IX oxidase (PPO), the last common enzyme of heme and chlorophyll biosynthesis, catalyses the oxidation of protoporphyrinogen IX to protoporphyrin IX, with FAD as cofactor. Among PPO, Bacillus subtilis PPO (bsPPO) is unique because of its broad substrate specificity
T A Ezhova et al.
Izvestiia Akademii nauk. Seriia biologicheskaia, (5)(5), 533-543 (2005-06-02)
Selective systems for screening Arabidopsis thaliana (L.) Heynh. mutants with altered sensitivity to the oxidative stress (OS) inductors norflurazon (NF), acifluorfen (AF), and plumbagin (PB) were developed and a collection of 28 mutants was obtained. Dwarf and necrotic forms predominated

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