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36197

Supelco

Phoxim

PESTANAL®, analytical standard

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About This Item

Fórmula empírica (notación de Hill):
C12H15N2O3PS
Número de CAS:
14816-18-3
Peso molecular:
298.30
EC Number:
238-887-3
MDL number:
MFCD00867617
UNSPSC Code:
41116107
PubChem Substance ID:
329755338
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCOP(=S)(OCC)O\N=C(/C#N)c1ccccc1

InChI

1S/C12H15N2O3PS/c1-3-15-18(19,16-4-2)17-14-12(10-13)11-8-6-5-7-9-11/h5-9H,3-4H2,1-2H3/b14-12+

InChI key

ATROHALUCMTWTB-WYMLVPIESA-N

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General description

Phoxims are classified under the organophosphorus group of pesticides.

Application

Phoxim may be used as an analytical reference standard for the determination of phoxim in:
  • Honeys, honeybees and pollens and food samples by QuEChERS extraction followed by analysis using liquid chromatography-electrospray ionization-tandem mass spectrometry (LC-ESI-LC-MS/MS) combined with multiple reaction monitoring (MRM) detection.
  • Egg samples by acetonitrile-based extraction and high performance liquid chromatography-diode array detection (HPLC-DAD).
  • Environmental samples by temperature-controlled ionic liquid dispersive liquid-phase extraction and HPLC combined with ultraviolet (UV) detection.

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Other Notes

blocked due to transport restrictions

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 2 Inhalation - Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - Skin Sens. 1

Storage Class

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCBW3465
SZBD039XV
SZBA019XV
SZBA019X
SZBA0

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Bing Li et al.
Chemosphere, 89(5), 609-614 (2012-06-12)
Phoxim insecticide is widely used in agriculture, which is toxic to insect pests and nontarget organisms. The phoxim poisoning is hard to prevent for silkworms. TiO(2) NPs have been widely applied in whitening, brightening foods, toothpaste or sunscreens, and orally-administered
Yongnian Ni et al.
Analytica chimica acta, 588(1), 131-139 (2007-03-28)
A sensitive and selective enzymatic kinetic method for the simultaneous determination of mixtures of carbaryl and phoxim pesticides was researched and developed. It was based on the inhibitory effect of the pesticides on acetylcholinesterase (AChE), and the use of 5,5'-dithiobis(2-nitrobenzoic)
G Hamscher et al.
Analytica chimica acta, 586(1-2), 330-335 (2007-03-28)
The poultry red mite Dermanyssus gallinae is the most important ectoparasite of poultry in several European countries. Phoxim is a well-known antiparasitic agent in wide use. Initial studies indicated that this compound could successfully be applied to eliminate D. gallinae
Jun-Yu Liang et al.
Foods (Basel, Switzerland), 9(3) (2020-03-20)
Investigations have indicated that storage pests pose a great threat to global food security by damaging food crops and other food products derived from plants. Essential oils are proven to have significant effects on a large number of stored grain
Yi Hui Zhang et al.
Archives of toxicology, 81(11), 785-792 (2007-05-31)
The hydrolysis of acetylthiocholine iodide (ATCh) by pralidoxime chloride (2-PAM Cl), trimedoxime (TMB(4)) and obidoxime chlpride (LUH(6)) was studied at pH 5.8-8.0 and incubation temperature from 5 to 40 degrees C in vitro. Significant ATCh hydrolysis by 2-PAM Cl, TMB(4)
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