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Merck

935611

Sigma-Aldrich

4-Vinyl-1,3-dioxolan-2-one

new
greener alternative

≥99.9%, anhydrous, battery grade

Sinónimos:

VEC, Vinyl ethylene carbonate

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About This Item

Fórmula empírica (notación de Hill):
C5H6O3
Número de CAS:
Peso molecular:
114.10
MDL number:
UNSPSC Code:
12352005

grade

battery grade

Quality Level

description

Application: Battery manufacturing

assay

≥99.9%

form

liquid

greener alternative product characteristics

Design for Energy Efficiency
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sustainability

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impurities

≤100 ppm H2O

refractive index

n20/D 1.45 (lit.)

bp

237 °C/733 mmHg (lit.)

density

1.188 g/mL at 25 °C (lit.)

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

SMILES string

C=CC1COC(=O)O1

InChI

1S/C5H6O3/c1-2-4-3-7-5(6)8-4/h2,4H,1,3H2

InChI key

BJWMSGRKJIOCNR-UHFFFAOYSA-N

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General description

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic organic compound with the molecular formula C5H6O3. It is a clear, colorless liquid with a high boiling point and is miscible with carbonate and ether solvents used in lithium-ion batteries (LIBs). Our battery grade VEC is differentiated by its high purity and low trace moisture to help ensure consistent performance in battery applications.
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Application

Anhydrous, battery grade 4-vinyl-1,3-dioxolan-2-one (VEC) is commonly used as an electrolyte additive in lithium-ion batteries (LIBs) to improve battery performance. VEC helps to form a stable film on the anode surface called a solid electrolyte interface (SEI). The SEI acts as a barrier that prevents further reaction between the electrolyte and the anode and thereby enhances the cyclic stability of the battery. For example, the addition of 2 wt.% VEC to the electrolyte formulation enhanced cycling performance in experiments both with Li metal anodes and graphite anodes In the electrolyte formulation, often VEC is added to be 2-10 wt.% of the solvent blend; however, scientists have even used VEC as the sole solvent in a lithium-metal battery with great results including long cycle life over 1000 cycles and reduced flammability

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pictograms

Skull and crossbones

signalword

Danger

hcodes

Hazard Classifications

Acute Tox. 3 Oral

Storage Class

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 1

flash_point_f

206.4 °F - closed cup

flash_point_c

96.9 °C - closed cup


Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

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Visite la Librería de documentos

Vinyl ethylene carbonate as an electrolyte additive for high-voltage LiNi0.4Mn0.4Co0.2O2/graphite Li-ion batteries
Zuo X, et al.
Ionics, 22, 201-208 (2016)
Highly safe and cyclable Li-metal batteries with vinylethylene carbonate electrolyte
Zhang Q, et al.
Nano Energy, 74, 104860-104860 (2020)
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes
Yang Y, et al.
ACS Applied Materials & Interfaces, 11, 6118-6125 (2019)

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