Saltar al contenido
Merck
Todas las fotos(1)

Documentos

427292

Sigma-Aldrich

1-Bromo-2-butyne

≥98%

Sinónimos:

1-(Bromomethyl)-2-methylacetylene, 2-Butyn-1-yl bromide, 2-Butynyl bromide, 4-Bromobut-2-yne

Iniciar sesiónpara Ver la Fijación de precios por contrato y de la organización
Todas las fotos(1)

About This Item

Fórmula lineal:
CH3C≡CCH2Br
Número de CAS:
3355-28-0
Peso molecular:
132.99
Beilstein/REAXYS Number:
605306
MDL number:
MFCD00190233
UNSPSC Code:
12352100
PubChem Substance ID:
24866752
NACRES:
NA.22

Quality Level

100

assay

≥98%

form

liquid

refractive index

n20/D 1.508 (lit.)

bp

40-41 °C/20 mmHg (lit.)

density

1.519 g/mL at 25 °C (lit.)

SMILES string

CC#CCBr

InChI

1S/C4H5Br/c1-2-3-4-5/h4H2,1H3

InChI key

LNNXOEHOXSYWLD-UHFFFAOYSA-N

¿Está buscando productos similares? Visita Guía de comparación de productos

Categorías relacionadas

General description

1-Bromo-2-butyne is a propargyl bromide derivative. It is one of the constitutional isomer of bromo butyne. Its Br-loss threshold photoionization breakdown diagram has been analyzed to derive dissociative photoionization thresholds to C4H5+ production. It participates in the preparation of linagliptin.

application

1-Bromo-2-butyne was used in the alkylation of L-tryptophan methyl ester. It was used as a source to generate CH3CCCH2 radicals to investigate the reaction kinetics of these radicals with NO and NO2.
It may be used in the synthesis of the following:
  • 4-butynyloxybenzene sulfonyl chloride
  • mono-propargylated diene derivative
  • isopropylbut-2-ynylamine
  • allenylcyclobutanol derivatives
  • allyl-[4-(but-2-ynyloxy)phenyl]sulfane
  • allenylindium
  • alkynyl alcohols
  • axially chiral teranyl compounds
Exploited in the synthesis of axially chiral teranyl compounds.

pictograms

Flame
GHS02

signalword

Warning

hcodes

H226

Hazard Classifications

Flam. Liq. 3

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

96.8 °F - closed cup

flash_point_c

36 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificados de análisis (COA)

Busque Certificados de análisis (COA) introduciendo el número de lote del producto. Los números de lote se encuentran en la etiqueta del producto después de las palabras «Lot» o «Batch»

¿Ya tiene este producto?

Encuentre la documentación para los productos que ha comprado recientemente en la Biblioteca de documentos.

Visite la Librería de documentos

Exploring the functional space of thiiranes as gelatinase inhibitors using click chemistry.
Testero SA, et al.
ARKIVOC (Gainesville, FL, United States), 7, 221-236 (2011)
Kinetics of resonance stabilized CH3CCCH2 radical reactions with NO and NO2.
Rissanen MP, et al.
Chemical Physics Letters, 543, 28-33 (2012)
Acetylenic TACE inhibitors. Part 1. SAR of the acyclic sulfonamide hydroxamates.
Levin JI, et al.
Bioorganic & Medicinal Chemistry Letters, 13(16), 2799-2803 (2003)
Takanori Shibata et al.
Journal of the American Chemical Society, 126(27), 8382-8383 (2004-07-09)
An asymmetric [2+2+2] cycloaddition of an alpha,omega-diyne, possessing ortho-substituted aryl groups on its terminus, and a monoalkyne with oxygen functionalities gave various axially chiral teraryl compounds. The coupling proceeded with extremely high enantio- (>99.5% ee) and diastereoselectivities (dl/meso = >95/5)
Imaging breakdown diagrams for bromobutyne isomers with photoelectron-photoion coincidence.
Bodi A and Hemberger P.
Physical Chemistry Chemical Physics, 16(2), 505-515 (2014)
Ver todos los artículos relacionados

Nuestro equipo de científicos tiene experiencia en todas las áreas de investigación: Ciencias de la vida, Ciencia de los materiales, Síntesis química, Cromatografía, Analítica y muchas otras.

Póngase en contacto con el Servicio técnico