302937

Perfluoro(methylcyclohexane)

technical grade, 90%

• Sinónimos: (Trifluoromethyl)undecafluorocyclohexane, Perfluoromethylcyclohexane
• Fórmula lineal: C₆F₁₁CF₃
• Número de CAS: 355-02-2
• Peso molecular: 350.05
• Beilstein/REAXYS Number: 1915981
• EC Number: 206-573-5
• MDL number: MFCD00001468
• UNSPSC Code: 12352100
• PubChem Substance ID: 24858283
• NACRES: NA.22

Propiedades

• grade: technical grade
• assay: 90%
• form: liquid
• refractive index: n17/D 1.285 (lit.)
• bp: 76 °C (lit.)
• density: 1.787 g/mL at 25 °C (lit.)
• SMILES string: FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C1(F)F
• InChI: 1S/C7F14/c8-1(7(19,20)21)2(9,10)4(13,14)6(17,18)5(15,16)3(1,11)12
• InChI key: QIROQPWSJUXOJC-UHFFFAOYSA-N

Descripción

General description

Mixtures of chloroform and perfluoro(methylcyclohexane) can be used as solvents for "fluorous" biphase reactions. Gas-phase structure of perfluoro(methylcyclohexane) was investigated.

Application

Perfluoro(methylcyclohexane) can be used as:

• A reactant to synthesize perfluoro-2-methylcyclohex-1-enolate by photochemical reaction with tetrabutylammonium iodide in water.
• A fluorous solvent to synthesize polynorbornene via ring-opening metathesis polymerization (ROMP) of norbornene using fluorous Grubbs′ second-generation catalyst.

It can also be used as a solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Perfluoro(methylcyclohexane) was employed as solvent to investigate fluorophilicity of a series of hydrocarbon and fluorocarbon-functionalized nicotinic acid esters.

Información de seguridad

• Storage Class: 10 - Combustible liquids
• wgk_germany: WGK 3
• flash_point_f: Not applicable
• flash_point_c: Not applicable
• ppe: Eyeshields, Gloves