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235016

Sigma-Aldrich

Dimethylphenylsilane

≥98%

Sinónimos:

Phenyldimethylsilane

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5 G
US$ 60,70
25 G
US$ 167,00

US$ 60,70

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5 G
US$ 60,70
25 G
US$ 167,00

About This Item

Fórmula lineal:
C6H5SiH(CH3)2
Número de CAS:
766-77-8
Peso molecular:
136.27
Beilstein:
2204906
Número CE:
212-170-5
Número MDL:
MFCD00008257
Código UNSPSC:
12352103
ID de la sustancia en PubChem:
24854073
NACRES:
NA.22

US$ 60,70

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Nivel de calidad

100

Ensayo

≥98%

Formulario

liquid

índice de refracción

n20/D 1.497 (lit.)

bp

157 °C/744 mmHg (lit.)

densidad

0.889 g/mL at 25 °C (lit.)

cadena SMILES

C[SiH](C)c1ccccc1

InChI

1S/C8H12Si/c1-9(2)8-6-4-3-5-7-8/h3-7,9H,1-2H3

Clave InChI

ZISUALSZTAEPJH-UHFFFAOYSA-N

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Descripción general

Dimethylphenylsilane is used as a silylating agent in homocoupling reactions to produce well defined polymers.[1] [2]

Aplicación

Reagent for enol ether synthesis.

Pictogramas

Flame
GHS02

Palabra de señalización

Warning

Frases de peligro

H226

Clasificaciones de peligro

Flam. Liq. 3

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 1

Punto de inflamabilidad (°F)

95.0 °F

Punto de inflamabilidad (°C)

35 °C

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
MKCX2888
MKCW0115
SHBJ6601
SHBJ4750
SHBH7754

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Diethylsilane 99%

Sigma-Aldrich

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Diethylsilane

B (C 6 F 5) 3-catalyzed group transfer polymerization of alkyl methacrylates with dimethylphenylsilane through in situ formation of silyl ketene acetal by B (C 6 F 5) 3-catalyzed 1, 4-hydrosilylation of methacrylate monomer
Chen, Yougen and Kitano
Open Journal of Polymer Chemistry, 6, 3502-3511 (2015)
Cu3 (BTC) 2 catalyzed dehydrogenative coupling of dimethylphenylsilane with phenol and homocoupling of dimethylphenylsilane to disiloxane
Anbu, Nagaraj, et,al
Journal of Colloid and Interface Science, 490, 430-435 (2017)
Slawomir Rubinsztajn et al.
Macromolecular rapid communications, 42(5), e2000601-e2000601 (2020-12-04)
The reaction of poly(hydromethylsiloxane-co-methylphenylsiloxane) with zirconium (IV) n-propoxide in dry toluene leads to extensive scission of the siloxane chain and conversion of Si-H groups. These processes produce oligomeric siloxanes and organosilanes containing moisture sensitive propoxy and siloxy-zirconate groups. The obtained

Questions

1–2 of 2 Questions  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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