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232807

Sigma-Aldrich

1,3-Dichloro-5,5-dimethylhydantoin

available chlorine 68 %

Sinónimos:

1,3-Dichloro-5,5-dimethyl-2,4-imidazolidinedione, DCDMH, NSC 33307, NSC 38630

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250 G
US$ 82,70
1 KG
US$ 154,00

US$ 82,70

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250 G
US$ 82,70
1 KG
US$ 154,00

About This Item

Fórmula empírica (notación de Hill):
C5H6Cl2N2O2
Número de CAS:
118-52-5
Peso molecular:
197.02
Beilstein:
146013
Número CE:
204-258-7
Número MDL:
MFCD00003190
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
24853931
NACRES:
NA.22

US$ 82,70

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Formulario

powder

composición

available chlorine, 68%

mp

132-134 °C (lit.)

solubilidad

water: soluble 0.21% at 25 °C(lit.)
carbon tetrachloride: freely soluble 12.5%(lit.)
chloroform: freely soluble 14%(lit.)
methylene chloride: freely soluble 30%(lit.)
benzene: freely soluble 9.2%(lit.)
chlorinated solvents: freely soluble at 25 °C(lit.)

cadena SMILES

CC1(C)N(Cl)C(=O)N(Cl)C1=O

InChI

1S/C5H6Cl2N2O2/c1-5(2)3(10)8(6)4(11)9(5)7/h1-2H3

Clave InChI

KEQGZUUPPQEDPF-UHFFFAOYSA-N

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Categorías relacionadas

Aplicación

1,3-Dichloro-5,5-dimethylhydantoin was used:
  • in reaction of chlorination of cytosine base[1]
  • in the synthesis of α-chloroacetophenones[2]
  • as an effective oxidizing agent for the oxidation of urazoles and bis-urazoles to their corresponding triazolinediones[3]
Reagent involved in:
  • Microwave-assisted aromatization of trisubstituted pyrazolines
  • Asymmetric chlorolactonization chlorenium source
  • Oxidative chlorination for the synthesis of arenesulfonyl chlorides
  • Selective halogenation for the synthesis of halo ketones
  • Chlorination reactions

Palabra de señalización

Danger

Frases de peligro

H272,H302,H315,H317,H410

Clasificaciones de peligro

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Ox. Sol. 2 - Skin Irrit. 2 - Skin Sens. 1

Riesgos supl.

EUH031

Código de clase de almacenamiento

5.1B - Oxidizing hazardous materials

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

345.2 °F

Punto de inflamabilidad (°C)

174 °C

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificados de análisis (COA)

Lot/Batch Number
MKCS9284
MKCR2638
MKCM7829
MKCG5830
MKBK2690V

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Radovan Buffa et al.
Carbohydrate polymers, 250, 116928-116928 (2020-10-15)
Electron-deficient chlorine covalently immobilised on an amido group of hyaluronic acid (HA) can be potentially exceptional for applications requiring biodegradable and biocompatible polymers with enhanced antibacterial or antiviral activity. This expectation is supported by the assumption that a small amount
a-Chlorination of Acetophenones Using 1, 3-Dichloro-5, 5-Dimethylhydantoin.
Xu Z, et al.
Synthetic Communications, 36(2), 255-258 (2006)
E J Olajos et al.
Journal of applied toxicology : JAT, 18(6), 409-420 (1998-12-05)
Vesication and skin irritation studies were conducted in hairless guinea-pigs to determine the vesicant and skin irritation potential of chemically-neutralized Chemical Agent Identification Sets (CAIS). The CAIS are training items that contain chemical warfare-related material--sulfur mustard (HD), nitrogen mustard (HN)
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The Journal of organic chemistry, 74(7), 2817-2823 (2009-03-03)
New 3'-terminal deoxyribonucleoside-loading reagents having a silyl-type linker were developed. They were effectively introduced into polymer supports under the conditions of Huisgen [3 + 2] cycloaddition without base protection. Moreover, four unmodified DNA oligomers d[TACCTAAATCCAX] (X = T, A, C
[Hygienic evaluation of the possible use of 1,3-dichloro-5,5-dimethylhydantoin for the purpose of drinking water decontamination].
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Gigiena i sanitariia, (3)(3), 11-13 (1982-03-01)
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Questions

1–2 of 2 Questions  

  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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