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16350

Sigma-Aldrich

Bromobenzene

≥99.5% (GC)

Sinónimos:

1-Bromobenzene, Bromobenzol, Monobromobenzene, Phenyl bromide

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100 ML
US$ 55,70
500 ML
US$ 159,00
1 L
US$ 234,00

US$ 55,70

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100 ML
US$ 55,70
500 ML
US$ 159,00
1 L
US$ 234,00

About This Item

Fórmula empírica (notación de Hill):
C6H5Br
Número de CAS:
108-86-1
Peso molecular:
157.01
Beilstein:
1236661
Número CE:
203-623-8
Número MDL:
MFCD00000055
Código UNSPSC:
12352100
ID de la sustancia en PubChem:
57647528
NACRES:
NA.22

US$ 55,70

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densidad de vapor

5.41 (vs air)

Nivel de calidad

200

presión de vapor

10 mmHg ( 40 °C)

Ensayo

≥99.5% (GC)

Formulario

liquid

temp. de autoignición

1051 °F

lim. expl.

36.5 %

índice de refracción

n20/D 1.559 (lit.)
n20/D 1.559

bp

156 °C (lit.)

mp

−31 °C (lit.)

solubilidad

alcohol: soluble 10.4g/100g at 25 °C
diethyl ether: soluble 71.3g/100g at 25 °C
water: insoluble 0.045g/100g at 30 °C (practically)
benzene: miscible
chloroform: miscible
hydrocarbons: miscible (petr.)

densidad

1.491 g/mL at 25 °C (lit.)

grupo funcional

bromo

cadena SMILES

Brc1ccccc1

InChI

1S/C6H5Br/c7-6-4-2-1-3-5-6/h1-5H

Clave InChI

QARVLSVVCXYDNA-UHFFFAOYSA-N

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Aplicación

Bromobenzene was used in the synthesis of four-armed star chain transfer agent required for preparation of amphiphilic star graft copolymers[1].

Acciones bioquímicas o fisiológicas

Bromobenzene induces hepatic necrosis via the formation of a reactive metabolite that arylates vital cellular macromolecules[2].

Palabra de señalización

Warning

Frases de peligro

H226,H315,H411

Clasificaciones de peligro

Aquatic Chronic 2 - Flam. Liq. 3 - Skin Irrit. 2

Código de clase de almacenamiento

3 - Flammable liquids

Clase de riesgo para el agua (WGK)

WGK 2

Punto de inflamabilidad (°F)

123.8 °F - closed cup

Punto de inflamabilidad (°C)

51.0 °C - closed cup

Equipo de protección personal

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificados de análisis (COA)

Lot/Batch Number
BCCM8940
BCCK2698
BCCH7377
BCCF7091
BCCC3505

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Si necesita una versión concreta, puede buscar un certificado específico por el número de lote.

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Star-like PAA-g-PPO well-defined amphiphilic graft copolymer synthesized by ATNRC and SET-NRC reaction.
Li Y, et al.
Journal of Polymer Science: Part A, General Papers, 48(10), 2084-2097 (2010)
Bromobenzene-induced liver necrosis. Protective role of glutathione and evidence for 3,4-bromobenzene oxide as the hepatotoxic metabolite.
D J Jollow et al.
Pharmacology, 11(3), 151-169 (1974-01-01)
Verónica Guilarte et al.
Organic letters, 13(19), 5100-5103 (2011-09-03)
An efficient synthesis of thiophenes and benzo[b]thiophenes has been developed from easily available bromoenynes and o-alkynylbromobenzene derivatives. This novel one-pot procedure involves a Pd-catalyzed C-S bond formation using a hydrogen sulfide surrogate followed by a heterocyclization reaction. Moreover, in situ
Yuning Ma et al.
Environmental science & technology, 46(24), 13112-13117 (2012-11-28)
The 2,4,6-tribromophenoxy moiety is a common structural feature of several brominated flame retardants, and we have previously reported on the environmental concentrations of one such compound, 1,2-bis(2,4,6-tribromophenoxy) ethane (TBE). Here we report the atmospheric concentrations of TBE and three other
Hiroyuki Asakura et al.
The journal of physical chemistry. A, 116(16), 4029-4034 (2012-04-14)
A homocoupling reaction mechanism of bromobenzene mediated by the [Ni(cod)(bpy)] (cod = 1,5-cyclooctadiene; bpy = 2,2'-bipyridine) complex was investigated by means of in situ time-resolved X-ray absorption fine structure (XAFS) and factor analysis. A dimer intermediate [Ni(bpy)(Ph)Br](2) proposed in the
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Questions

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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

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    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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