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CRM05286

Supelco

Ethiofencarb

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

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About This Item

Empirical Formula (Hill Notation):
C11H15NO2S
CAS Number:
Molecular Weight:
225.31
Beilstein:
2973224
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24

grade

certified reference material
TraceCERT®

Quality Level

product line

TraceCERT®

form

solid

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

storage temp.

2-8°C

SMILES string

CCSCc1ccccc1OC(=O)NC

InChI

1S/C11H15NO2S/c1-3-15-8-9-6-4-5-7-10(9)14-11(13)12-2/h4-7H,3,8H2,1-2H3,(H,12,13)

InChI key

HEZNVIYQEUHLNI-UHFFFAOYSA-N

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General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. The CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Ethiofencarb is a carbamate insecticide used to control aphids on pome fruit, stone fruit, soft fruit, vegetables, ornamentals, and sugar beets. It is an acetylcholinesterase (AChE) inhibitor and gets activated by both contact and ingestion, absorbed by leaves and roots.
As per the commission regulation no 1107/2009, regarding the use of plant protection products and repealing the council directive 91/414/EEC, ethiofencarb is not allowed for use in the European Union. The default maximum residue limit (MRL) for ethiofencarb is 0.01 mg/kg according to the Article 18(b) Reg 396/2005.

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The CRM may also find the following uses:

  • Estimation of systemic and non-systemic pesticides in 80 samples of apples from Kazakhstan by LC-MS/MS and GC-MS/MS
  • Development of a method for rapid multi-residue screening of 12 pesticides and 7 mycotoxins in grain and animal feed samples using flow injection (FI) mass spectrometry (MS)
  • UHPLC-MS/MS determination of carbamate pesticide residues in fresh herb samples for human consumption and an optimized QuEChERS extraction
  • Study the photocatalytic degradation of ethiofencarb in the presence of a chalcogenide, SnI4S8
  • Differentiation between structurally isomeric pesticides using high-resolution accurate mass analyzers
  • Multi-residue analysis of 250 pesticides by ultra-performance liquid chromatography (UHPLC) coupled to MS/MS in processed fruits

Recommended products

Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany

Pictograms

Exclamation markEnvironment

Signal Word

Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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Alberto Nuñez et al.
Toxics, 6(4), 59-59 (2018-10-04)
Structural isomeric pesticides are used in agriculture and may be challenging to differentiate for accurate identification in pesticide monitoring programs. Due to structural similarity, isomeric pesticides are difficult to separate chromatographically, and thus, their accurate identification may rely solely on
Evaluation of flow injection mass spectrometry approach for rapid screening of selected pesticides and mycotoxins in grain and animal feed samples
Sapozhnikova Y, et al.
Food Control, 116, 107323-107323 (2020)
Chiing-Chang Chen et al.
Nanomaterials (Basel, Switzerland), 11(5), 1325-1325 (2021-06-03)
This work reports the preparation and detailed characterization of stannum indium sulfide (SnIn4S8) semiconductor photocatalyst for degradation of ethiofencarb (toxic insecticide) under visible-light irradiation. The as-prepared SnIn4S8 showed catalytic efficiency of 98% in 24 h under optimal operating conditions (pH
Systemic and non-systemic pesticides in apples from Kazakhstan and their impact on human health
Lozowicka B, et al.
Journal of food composition and analysis, 90, 103494-103494 (2020)
Edouard Akono Nantia et al.
Food chemistry, 216, 334-341 (2016-09-07)
A new reliable, fast and highly sensitive method based on ultra-high performance liquid chromatography tandem mass spectrometry has been developed and validated for the determination of 28 carbamates in aromatic herbs. A modified QuEChERS-based method was optimized for the extraction

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