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19-2380

Sigma-Aldrich

Methyl acrylate

SAJ first grade, ≥99.0%

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About This Item

Linear Formula:
CH2=CHCOOCH3
CAS Number:
96-33-3
Molecular Weight:
86.09
Beilstein:
605396
EC Number:
202-500-6
MDL number:
MFCD00008627
UNSPSC Code:
12352108
PubChem Substance ID:
329751696
grade:
SAJ first grade
Assay:
≥99.0%
bp:
80 °C (lit.)
vapor pressure:
67.5 mmHg ( 20 °C)
Pricing and availability is not currently available.

grade

SAJ first grade

vapor density

3 (vs air)

vapor pressure

67.5 mmHg ( 20 °C)

Assay

≥99.0%

form

liquid

autoignition temp.

874 °F

expl. lim.

14.5 %

availability

available only in Japan

refractive index

n20/D 1.402 (lit.)

bp

80 °C (lit.)

mp

−75 °C (lit.)

density

0.956 g/mL at 25 °C (lit.)

SMILES string

COC(=O)C=C

InChI

1S/C4H6O2/c1-3-4(5)6-2/h3H,1H2,2H3

InChI key

BAPJBEWLBFYGME-UHFFFAOYSA-N

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Pictograms

FlameSkull and crossbones
GHS02,GHS06

Signal Word

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Irrit. 2 - Flam. Liq. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

27.0 °F - closed cup

Flash Point(C)

-2.8 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
A5141
A8761
A5638
A3547
A1481

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Xin Liu et al.
Journal of hazardous materials, 175(1-3), 1014-1021 (2009-11-27)
Porous acrylonitrile (AN)/methyl acrylate (MA) copolymer beads were prepared by suspended emulsion polymerization. The cyano groups in AN/MA copolymer beads were converted to amidoxime (AO) groups by reaction with hydroxylamine hydrochloride (NH(2)OH.HCl) to remove metal ions in aqueous solution. The
Transformation of nickelalactones to methyl acrylate: on the way to a catalytic conversion of carbon dioxide.
S Y Tina Lee et al.
ChemSusChem, 4(9), 1275-1279 (2011-09-17)
Nicky Chan et al.
Macromolecular rapid communications, 32(7), 604-609 (2011-03-26)
The use of copper tubing as both the reactor and as a catalyst source is demonstrated for continuous controlled radical polymerization of methyl acrylate at ambient temperature and at low solvent content of 30%. The high surface area provided by
Boris Neuwald et al.
Journal of the American Chemical Society, 135(3), 1026-1036 (2012-12-22)
Various phosphinesulfonato ligands and the corresponding palladium complexes [{((P^O)PdMeCl)-μ-M}(n)] ([{((X)1-Cl)-μ-M}(n)], (P^O) = κ(2)-P,O-Ar(2)PC(6)H(4)SO(2)O) with symmetric (Ar = 2-MeOC(6)H(4), 2-CF(3)C(6)H(4), 2,6-(MeO)(2)C(6)H(3), 2,6-(iPrO)(2)C(6)H(3), 2-(2',6'-(MeO)(2)C(6)H(3))C(6)H(4)) and asymmetric substituted phosphorus atoms (Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2'-(2,6-(MeO)(2)C(6)H(3))C(6)H(4); Ar(1) = 2,6-(MeO)(2)C(6)H(3), Ar(2) = 2-cHexOC(6)H(4)) were
María B Blanco et al.
Environmental science & technology, 44(18), 7031-7036 (2010-08-24)
A product study is reported on the gas-phase reactions of OH radicals and Cl atoms with methyl acrylate. The experiments were performed in a 1080-L quartz-glass chamber in synthetic air at 298 ± 2 K and 760 ± 10 Torr
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