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940178

Sigma-Aldrich

Manganese (II) sulfate monohydrate

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≥99.9% trace metals basis

Synonym(s):

Manganese(2+) sulfate monohydrate, Manganous sulfate monohydrate

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About This Item

Empirical Formula (Hill Notation):
MnSO4. H2O
CAS Number:
Molecular Weight:
169.02
UNSPSC Code:
12141502

Quality Level

Assay

(Complexiometric EDTA)
≥99.9% trace metals basis

form

powder or crystals

solubility

water: soluble

anion traces

chloride (Cl-): ≤20 ppm

cation traces

Al: ≤10 ppm
Ca: ≤10 ppm
Cd: ≤10 ppm
Cr: ≤10 ppm
Fe: ≤10 ppm
K: ≤10 ppm
Mg: ≤10 ppm
Na: ≤30 ppm
Ni: ≤10 ppm
Pb: ≤10 ppm
Si: ≤10 ppm
Zn: ≤10 ppm

SMILES string

O=S(=O)=[Mn](=O)=O.O

General description

Manganese Sulfate Monohydrate is a compound with moderate solubility in water, serving as a significant source of both manganese and sulfur. It exhibits slight solubility in methanol. Manganese Sulfate Monohydrate plays a critical role as a precursor salt in the synthesis of cathode active materials for Lithium-ion batteries. Our Manganese Sulfate Monohydrate with 99.9% purity is suitable for the Reserach and devlopemnt application of Batteries.

Application

Manganese Sulfate Monohydrate is widely utilized in research and development (R&D), particularly in the field of batteries for the synthesis of cathode active materials. Its notable uses include:













  • Synthesizing LiNi0.6Co0.2Mn0.2O2 cathode materials for Lithium-ion batteries using co-precipitation method.
  • Synthesis of layered Li–excess nickel–manganese oxides (LLNMO) via a coprecipitation method using precursor salts of NiSO4·6H2O and MnSO4·H2O.
  • Creation of zirconium-doped lithium-rich layered oxide materials with porous hollow structure using salt precursors of NiSO4·6H2O, CoSO4·7H2O, and MnSO4·H2O.
  • Addition to the electrolyte solution for depositing a porous Ni-P alloy thin film using an electroless process to improve the film′s properties and create an embedded resistor with enhanced electrical resistance, suitable for specific resistance values in electronic applications.

Features and Benefits

  1. Tested with ICP for confirming the requirements of purity (<=1000 ppm)
  2. Minimum heavy metal contents in ppm level (<=10 ppm)
  3. water soluble

Signal Word

Danger

Hazard Statements

Hazard Classifications

Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 Inhalation

Target Organs

Brain

Storage Class Code

11 - Combustible Solids

WGK

WGK 2

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Co?precipitation synthesis of Ni0.6Co0.2Mn0.2(OH)2precursor and characterization of LiNi0.6Co0.2Mn0.2O2 cathode material for secondary lithium batteries
Liang L, et al.
Electrochimica Acta, 130, 82-89 (2014)
Electrochemical performance of zirconium doped lithium rich layered Li1.2Mn0.54Ni0.13Co0.13O2 oxide with porous hollow structure
He Z, et al.
Journal of Power Sources, 299, 334-341 (2015)
Fabrication of a novel porous Ni?P thin-film using electroless-plating: Application to embedded thin-film resistor Author links open overlay panel
Zhou G, et al.
Materials Letters, 108, 75-78 (2013)
Critical Role of Oxygen Evolved from Layered Li?Excess Metal Oxides in Lithium Rechargeable Batteries
Hong J, et al.
Chemistry of Materials, 24(14), 2692?2697-2692?2697 (2012)

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