71620
Sodium hydride
powder (moistened with oil), 55-65% (gas-volumetric)
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About This Item
Linear Formula:
NaH
CAS Number:
Molecular Weight:
24.00
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.23
Recommended Products
form
powder (moistened with oil)
reaction suitability
reagent type: reductant
concentration
55-65% (gas-volumetric)
mp
800 °C (dec.) (lit.)
SMILES string
[Na]
InChI
1S/Na.H
InChI key
MPMYQQHEHYDOCL-UHFFFAOYSA-N
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General description
Sodium hydride can be easily formed by reacting sodium metal with hydrogen gas at elevated temperatures. NaH is highly sensitive to moisture and air. It may be used as a strong reducing agent in the deintercalation of topotactic oxide. The crystal structure constitutes of a cubic Na with interstitial hydride ions. Sodium hydride exhibits a high gravimetric hydrogen storage capacity.
Application
Direct intercalation into C60 results in the superconducting material (NaH)4C60.
Packaging
Packed in plastic bag, which is soluble at 45-60 °C in hydrocarbons, THF and dioxane.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Met. Corr. 1 - Water-react 1
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Sodium hydride as a powerful reducing agent for topotactic oxide deintercalation: Synthesis and characterization of the nickel (I) oxide LaNiO2.
Hayward MA, et al.
Journal of the American Chemical Society, 121(38), 8843-8854 (1999)
Shuo Xing et al.
Organic & biomolecular chemistry, 13(5), 1515-1520 (2014-12-06)
A novel synthetic route leading to N-glycolyl muramyl dipeptide (MDP), a bacterial glycopeptide of particular interest in studies of nucleotide-binding oligomerization domain-containing protein 2 (NOD2), is described. The synthetic strategy hinges on the alkylation of benzylidene-protected glucal with 2-bromopropionic acid
Nanoarchitecture of Protective Coatings for Air Sensitive Metal Hydrides
Dobbins T
Material Matters, 2(2), 19-19 (2007)
Hiroshi Fukasawa et al.
ACS chemical neuroscience, 5(7), 525-532 (2014-04-18)
Neuropathic pain is a chronic condition resulting from neuronal damage. Pregabalin, the (S)-isomer of 3-isobutyl-γ-aminobutyric acid (GABA), is widely used to treat neuropathic pain, despite the occurrence of central nervous system (CNS)-related side effects such as dizziness and somnolence. Here
Formation of Crystalline Sodium Hydride Nanoparticles Encapsulated Within an Amorphous Framework.
Sartbaeva A, et al.
Journal of Cluster Science, 21(3), 543-549 null
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