If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
185558
Benzyl chloride
ReagentPlus®, 99%, contains ≤1% propylene oxide as stabilizer
Synonym(s):
α-Chlorotoluene
About This Item
Recommended Products
vapor density
4.36 (vs air)
Quality Level
vapor pressure
10.3 mmHg ( 60 °C)
7 mmHg ( 55 °C)
product line
ReagentPlus®
Assay
99%
form
liquid
autoignition temp.
1085 °F
contains
≤1% propylene oxide as stabilizer
expl. lim.
14 %
refractive index
n20/D 1.538 (lit.)
bp
177-181 °C (lit.)
mp
−43 °C (lit.)
solubility
0.46 g/L at 30 °C (Decomposes in contact with water)
density
1.1 g/mL at 25 °C (lit.)
functional group
chloro
phenyl
SMILES string
ClCc1ccccc1
InChI
1S/C7H7Cl/c8-6-7-4-2-1-3-5-7/h1-5H,6H2
InChI key
KCXMKQUNVWSEMD-UHFFFAOYSA-N
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General description
Application
- A benzylating agent for the benzylation of benzene and other aromatic compounds.[1][2]
- A reactant for the preparation of 4-methoxydiphenylmethane by Friedel-Crafts alkylation with anisole.[3]
It can also be used to introduce the benzyl protecting group to alcohols and carboxylic acids by forming corresponding benzyl ether, and benzyl ester, respectively.[1][4]
Legal Information
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 1B - Eye Dam. 1 - Muta. 1B - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 Oral - STOT SE 3
Target Organs
Heart,forestomach, Respiratory system
Storage Class Code
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
Flash Point(F)
152.6 °F - closed cup
Flash Point(C)
67 °C - closed cup
Personal Protective Equipment
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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