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152307

Sigma-Aldrich

3-Hydroxypyridine-2-carboxylic acid

98%

Synonym(s):

3-Hydroxypicolinic acid, 3-HPA, 3-Hydroxypyridine-2-carboxylic acid

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About This Item

Empirical Formula (Hill Notation):
C6H5NO3
CAS Number:
874-24-8
Molecular Weight:
139.11
Beilstein:
118954
EC Number:
212-859-0
MDL number:
MFCD00006294
UNSPSC Code:
12352100
PubChem Substance ID:
24849221
NACRES:
NA.22

Assay

98%

form

powder or crystals

mp

213-218 °C (lit.)

SMILES string

OC(=O)c1ncccc1O

InChI

1S/C6H5NO3/c8-4-2-1-3-7-5(4)6(9)10/h1-3,8H,(H,9,10)

InChI key

BRARRAHGNDUELT-UHFFFAOYSA-N

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Application

Ligand for a variety of metal complexes including Hg(II), and Sm(III).

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Misaki Nakai et al.
Journal of inorganic biochemistry, 98(1), 105-112 (2003-12-09)
Two chargeless VO(IV) complexes with 3-hydroxypyridine-2-carboxylic acid (H2hpic), [VO(Hhpic-O,O)(Hhpic-O,N)(H2O)].3H2O (1) and the cyclic tetramer [(VO)4(mu-(hpic-O,O',N))4(H2O)4].8H3O (2), have been synthesized and characterized by elemental analysis, mass, infrared, electronic absorption, electron spin resonance (ESR) spectroscopies, and X-ray crystallography. Their coordination structures are
Polyhedron, 26, 1045-1045 (2007)
Polyhedron, 25, 2471-2471 (2006)
K J Wu et al.
Rapid communications in mass spectrometry : RCM, 7(2), 142-146 (1993-02-01)
Matrix-assisted laser desorption time-of-flight mass spectrometry has been used to produce quasi-molecular ion signals from underivatized mixed-base single-stranded DNA oligomers ranging from 10 to 67 nucleotides in length. These results were obtained with a new matrix material, 3-hydroxypicolinic acid (3-hydroxypyridine-2-carboxylic
Shintaro Kodama et al.
Dalton transactions (Cambridge, England : 2003), (44)(44), 9708-9711 (2009-11-04)
Vanadium(iv) complexes bearing 3-hydroxypicolinic acid (H(2)hpic) as ligands, VO(Hhpic)(2) (1) and the cyclic tetramer (VO)(4)(hpic)(4) (2), have excellent catalytic ability for the oxidation of a variety of primary and secondary benzyl alcohols with molecular oxygen in acetonitrile or protic solvents
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