- Short and efficient synthetic route to methyl α-trioxacarcinoside B and anomerically activated derivatives.
Short and efficient synthetic route to methyl α-trioxacarcinoside B and anomerically activated derivatives.
Organic letters (2011-10-01)
Thomas Magauer, Andrew G Myers
PMID21958151
ABSTRACT
A 9-step synthetic route to the complex carbohydrate methyl α-trioxacarcinoside B from 2-acetylfuran is described. Anomerically activated forms, including 1-phenylthio, 1-O-(4'-pentenyl), 1-fluoro, and 1-O-acetyl derivatives are also prepared.