CRM01399
Teflubenzuron
certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
Synonym(s):
Clofentezine
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About This Item
Empirical Formula (Hill Notation):
C14H6Cl2F4N2O2
CAS Number:
Molecular Weight:
381.11
Beilstein:
8229925
MDL number:
UNSPSC Code:
41116107
NACRES:
NA.24
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grade
certified reference material
TraceCERT®
Quality Level
product line
TraceCERT®
shelf life
limited shelf life, expiry date on the label
manufacturer/tradename
Manufactured by: Sigma-Aldrich Production GmbH, Switzerland
storage temp.
2-8°C
SMILES string
Fc1cccc(F)c1C(=O)NC(=O)Nc2cc(Cl)c(F)c(Cl)c2F
InChI
1S/C14H6Cl2F4N2O2/c15-5-4-8(12(20)10(16)11(5)19)21-14(24)22-13(23)9-6(17)2-1-3-7(9)18/h1-4H,(H2,21,22,23,24)
InChI key
CJDWRQLODFKPEL-UHFFFAOYSA-N
General description
This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Teflubenzuron is a type of benzoylurea insecticide that disrupts the chitin deposition in the insect cuticle by inhibiting chitin synthesis and molting. It is a systemic insect growth regulator used for the control of lepidoptera, coleoptera, diptera, aleyrodidae, hymenoptera, psyllidae, and hemiptera larvae in vines, pome fruit, stone fruit, citrus, cabbages, potatoes, vegetables, soybeans, trees, sorghum, tobacco, and cotton. It is also used to control fly and mosquito larvae and immature stages of locusts.
Teflubenzuron was included to the Annex I of Directive 91/414/EEC on 01 December 2009. Teflubenzuron is not approved for use in the European Union (EU). But the Annexe IIIA of Regulation (EC) No 396/2005 establishes the maximum residue levels (MRLs) of teflubenzuron in the range of 0.01–5 mg/kg in fruits, vegetables, crops, and livestock. Teflubenzuron is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Teflubenzuron is a type of benzoylurea insecticide that disrupts the chitin deposition in the insect cuticle by inhibiting chitin synthesis and molting. It is a systemic insect growth regulator used for the control of lepidoptera, coleoptera, diptera, aleyrodidae, hymenoptera, psyllidae, and hemiptera larvae in vines, pome fruit, stone fruit, citrus, cabbages, potatoes, vegetables, soybeans, trees, sorghum, tobacco, and cotton. It is also used to control fly and mosquito larvae and immature stages of locusts.
Teflubenzuron was included to the Annex I of Directive 91/414/EEC on 01 December 2009. Teflubenzuron is not approved for use in the European Union (EU). But the Annexe IIIA of Regulation (EC) No 396/2005 establishes the maximum residue levels (MRLs) of teflubenzuron in the range of 0.01–5 mg/kg in fruits, vegetables, crops, and livestock. Teflubenzuron is monitored in the Multiannual Control Programmes for Pesticides Residues (MACP), run within the EU and EFTA in/on products of plant origin.
Application
It is intended to be used as a certified reference material (CRM) for calibration in chromatography and other analytical techniques.
The teflubenzuron certified reference material (CRM) may also find use as given below:
The teflubenzuron certified reference material (CRM) may also find use as given below:
- Determination of 9 benzoylurea insecticides in fruit, vegetable, cereal, and animal product samples by pressurized liquid extraction and LC-MS/MS
- Simultaneous analysis of lufenuron, bifenthrin, and teflubenzuron residues in coconut water by matrix solid-phase dispersion extraction combined with reversed-phase high-performance liquid chromatography
- Development of a high performance liquid chromatography–triple quadrupole mass spectrometry (HPLC-MS/MS) based method for the simultaneous estimation of 7 benzoylurea insecticides in infused oolong tea
- Multi-residue analysis of pesticides in Açai fruit by an extraction based on matrix solid phase dispersion and determination using liquid chromatography
- Comparative study for the extraction of 9 benzoylurea insecticides using two dispersive liquid-liquid microextraction (DLLME) approaches from wastewater samples followed by their determination using liquid chromatography-quadrupole-linear ion trap-mass spectrometry
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Find a digital Reference Material for this product available on our online platform ChemisTwin® for NMR. You can use this digital equivalent on ChemisTwin® for your sample identity confirmation and compound quantification (with digital external standard). An NMR spectrum of this substance can be viewed and an online comparison against your sample can be performed with a few mouseclicks. Learn more here and start your free trial.
Legal Information
TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 2
Target Organs
Liver
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
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Multi-residue determination of pesticides in acai tropical fruit (Euterpe oleracea) by matrix solid-phase dispersion combined with liquid chromatography
Fr?es, M B R, et al.
Food Analytical Methods, 328-333 null
Lei Chen et al.
Food chemistry, 143, 405-410 (2013-09-24)
A method for the simultaneous determination of 7 benzoylurea pesticides (chlorfluazuron, diflubenzuron, fluazuron, flufenoxuron, hexaflumuron, teflubenzuron and triflumuron) in the manufactured Oolong tea leaves and its infusion was described. The method has a LOD of 0.03-1.00ng/mL, a recovery of 90.4-103%
Reasoned opinion on the review of the existing maximum residue levels (MRLs) for teflubenzuron according to Article 12 of Regulation (EC) No 396/2005
European Food Safety Authority
EFSA Journal, 3664 null
A reversed-phase high-performance liquid chromatography method combined with matrix solid-phase dispersion extraction for the determination of teflubenzuron, lufenuron and bifenthrin residues in lyophilized coconut water
Santos L F S, et al.
Journal of food composition and analysis, 183-188 null
Monia Brutti et al.
Journal of separation science, 33(1), 1-10 (2010-01-22)
A method based on pressurized liquid extraction and LC-MS/MS has been developed for determining nine benzoylureas (BUs) in fruit, vegetable, cereals, and animal products. Samples (5 g) were homogenized with diatomaceous earth and extracted in a 22 mL cell with
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