38912
Dimethyl ether
puriss., ≥99.9% (GC)
Synonym(s):
Methyl ether
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About This Item
Linear Formula:
(CH3)2O
CAS Number:
Molecular Weight:
46.07
Beilstein:
1730743
EC Number:
MDL number:
UNSPSC Code:
12142100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
vapor density
1.62 (vs air)
vapor pressure
>760 mmHg ( 25 °C)
grade
puriss.
Assay
≥99.9% (GC)
autoignition temp.
662 °F
expl. lim.
27 %
bp
−24.8 °C (lit.)
mp
−141 °C (lit.)
functional group
ether
SMILES string
COC
InChI
1S/C2H6O/c1-3-2/h1-2H3
InChI key
LCGLNKUTAGEVQW-UHFFFAOYSA-N
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General description
Dimethyl ether (DME) is the simplest aliphatic ether used as a reactant as well as a solvent in organic synthesis. It is also used as a precursor for the preparation of important useful organic compounds such as dimethyl carbonate, methyl acetate, propylene and chloromethyl ether.
Application
DME can be used as a precursor for the preparation of versatile methylating agents such as dimethyl sulfate and trimethyloxonium tetrafluoroborate.
Packaging
Cylinder with net 1.1 kg
DIN 477 nr.1
Other Notes
Sales restrictions may apply
Recommended products
Z742161 DIN 1 Regulator OR 99112 outlet Valve
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Flam. Gas 1A - Press. Gas Liquefied gas
Storage Class Code
2A - Gases
WGK
WGK 1
Flash Point(F)
-41.8 °F - closed cup
Flash Point(C)
-41 °C - closed cup
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Dimethyl ether
Muller M, et al.
Ullmann's Encyclopedia of Industrial Chemistry, 156(2), 497-511 (2000)
Trimethyloxonium tetrafluoroborate
Curphey, TJ
Organic Syntheses, 50(4), 1019-1023 (1988)
Direct dimethyl ether synthesis
Ogawa T, et al.
Journal of natural gas chemistry, 12(4), 219-227 (2003)
Dimethyl ether (DME) as an alternative fuel
Semelsberger TA, et al.
Journal of Power Sources, 156(2), 497-511 (2006)
Salma Parveen et al.
The journal of physical chemistry. A, 113(21), 6182-6191 (2009-05-09)
Theoretical calculations have been carried out using ab initio MP2 and B3LYP density functional methods to investigate the interaction between fluorinated dimethyl ethers (nF = 1-5) and water. Depending on the number of F atoms implanted on the dimethyl ethers
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