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935905

Sigma-Aldrich

Fluoroethylene carbonate

greener alternative

Technipur®, 99% (GC)

Synonym(s):

4-Fluoro-1,3-dioxolan-2-one, FEC

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About This Item

Empirical Formula (Hill Notation):
C3H3FO3
CAS Number:
Molecular Weight:
106.05
MDL number:
UNSPSC Code:
26111700
NACRES:
NA.21

Quality Level

Assay

99% (GC)

form

solid

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

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bp

212 °C

mp

18-23 °C

density

1.485 g/cm3

application(s)

battery manufacturing

greener alternative category

storage temp.

2-8°C

SMILES string

FC1COC(=O)O1

InChI

1S/C3H3FO3/c4-2-1-6-3(5)7-2/h2H,1H2

InChI key

SBLRHMKNNHXPHG-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which belongs to one of the four categories of greener alternatives. Fluoroethylene carbonate is an enabling product, used as an electrolyte additive and is helpful to improve the performance of batteries, thus has been enhanced for energy efficency. Click here for more information.

Application

Fluoroethylene carbonate (FEC) is widely used as electrolyte additive in lithium ion batteries. As an additive, it helps in enhancing the electrochemical performance of Si/graphite-anodes in Li-ion batteries.

Legal Information

"Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany"
Technipur is a registered trademark of Merck KGaA, Darmstadt, Germany

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Warning

Hazard Statements

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1

Storage Class Code

11 - Combustible Solids

WGK

WGK 1

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


Certificates of Analysis (COA)

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Fluoroethylene carbonate electrolyte and its use in lithium ion batteries with graphite anodes
McMillan R, et al.
Journal of Power Sources, 81, 20-26 (1999)
Understanding fluoroethylene carbonate and vinylene carbonate based electrolytes for Si anodes in lithium ion batteries with NMR spectroscopy
Yanting J, et al.
Journal of the American Chemical Society, 140(31), 9854-9867 (2018)
Understanding the thermal instability of fluoroethylene carbonate in LiPF6-based electrolytes for lithium ion batteries
Kim K, et al.
Electrochimica Acta, 225, 358-368 (2017)
Electrochemical characteristics of amorphous silicon thin film electrode with fluoroethylene carbonate additive
Kim J S, et al.
Current Applied Physics, 14, 596-602 (2014)
A new insight into the content effect of fluoroethylene carbonate as a film forming additive for lithium-ion batteries
Zhao X, et al.
International Journal of Electrochemical Science, 10, 2515-2534 (2015)

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