935719

Cobalt(II) nitrate hexahydrate

≥99.9% trace metals basis

• Synonym(s): Cobalt Nitrate Hexahydrate, Cobalt dinitrate hexahydrate, Cobaltous nitrate, Cobaltous nitrate hexahydrate, Nitric acid, cobalt(II) salt
• Linear Formula: Co(NO₃)₂ · 6H₂O
• CAS Number: 10026-22-9
• Molecular Weight: 291.03
• MDL number: MFCD00149647
• UNSPSC Code: 12352302
• NACRES: NA.21

Properties

• Quality Level: 200
• Assay: ≥99.9% trace metals basis
• form: powder, crystals or granules (Chunks)
• greener alternative product characteristics: Design for Energy Efficiency; Learn more about the Principles of Green Chemistry.
• sustainability: Greener Alternative Product
• color: faint red to very dark red
• mp: 55 °C (lit.)
• solubility: soluble, clear to slightly hazy
• greener alternative category: Enabling
• SMILES string: O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O
• InChI: 1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;
• InChI key: QGUAJWGNOXCYJF-UHFFFAOYSA-N

Description

General description

Cobalt(II)nitrate hexahydrate is red solid which is soluble in water and polar solvents. It is also known as hexaaquacobalt(II) nitrate consists of [Co(OH₂)₆]²⁺ and [NO₃]⁻ ions.

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Application

Cobalt(II) nitrate hexahydrate, has been widely used for the synthesis of Cobalt oxide nanoparticles and cobalt containing compounds. For Example:Cobalt(II) nitrate hexahydrate is used to synthesize cobalt-cobalt oxide/N-doped carbon hybrids, which are then used as hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalysts in water splitting.

It has also been used as a primary precursor material in the synthesis of Co₃O₄ nanocrystals in various shapes such as nanosheets, nanocubes, and nanobelts as a catalyst for methane combustion.

Furthermore, the reaction of Cobalt(II) nitrate hexahydrate with Nickel(II) nitrate hexahydrate produces Nickel-cobalt layered double hydroxide nanosheets in presence of methanol and CTAB, which is used as a high-performance electrocatalyst for oxygen evolution.

In addition, Cobalt(II) nitrate hexahydrate precursor powder is calcined to produce Co₃O₄ nanotubes using the template synthesis method. The Co₃O₄ nano-tubes, nanorods, and nanoparticles that have been created are used in gas sensing systems and as anode materials for Li-ion batteries

Cobalt hydroxide and layered double hydroxides (CH@LDH) have been synthesized using Cobalt(II)nitrate hexahydrate as a sulfur host for lithium–sulfur batteries.

It is well studied that, Cobalt(II) nitrate hexahydrate is used as a heterogeneous catalyst Co/SiO₂ with Silica support, for Fischer−Tropsch Synthesis.

Cobalt(II) Nitrate Hexahydrate is also used as a catalyst for the synthesis of 5-Carboxanilide-dihydropyrimidinone derivatives by the condensation reaction of acetoacetanilide, aldehyde and urea/thiourea.

Safety Information

• Pictograms: GHS03,GHS08,GHS05,GHS07,GHS09
• Signal Word: Danger
• Hazard Statements: H272,H302,H317,H318,H334,H341,H350i,H360FD,H373,H410
• Precautionary Statements: P210 - P273 - P280 - P301 + P312 - P305 + P351 + P338 - P308 + P313
• Hazard Classifications: Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation
• Target Organs: Lungs
• Storage Class Code: 5.1B - Oxidizing hazardous materials
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable