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912646

Sigma-Aldrich

tBuBrettPhos Pd G6 bromide

Synonym(s):

tBuBrettPhos OAC precatalyst Br

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About This Item

Empirical Formula (Hill Notation):
C38H53BrF3O2PPd
Molecular Weight:
816.12
UNSPSC Code:
12161600
NACRES:
NA.22

Pricing and availability is not currently available.

form

powder or crystals

Quality Level

reaction suitability

reagent type: catalyst
reaction type: Cross Couplings

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This Item
EZHSEZBRAIN42EZHS42
species reactivity

human

species reactivity

human

species reactivity

human

species reactivity

human

assay range

sensitivity: 6.0 pg/mL
(50 μl sample size), standard curve range: 16-500 pg/mL

assay range

-

assay range

sensitivity: 8 pg/mL
(lowest level of Amyloid β1-42 standard; 50 μL sample size), standard curve range: 16-500 pg/mL

assay range

sensitivity: 8.0 pg/mL
(50 μl sample size), standard curve range: 16-500 pg/mL

input

sample type plasma (K2 EDTA)
sample type serum
sample type cerebrospinal fluid (CSF)

input

-

input

sample type tissue/cellular lysate

input

sample type plasma (K2 EDTA)
sample type serum
sample type cerebrospinal fluid (CSF)

Quality Level

200

Quality Level

100

Quality Level

200

Quality Level

200

technique(s)

ELISA: suitable

technique(s)

ELISA: suitable

technique(s)

ELISA: suitable

technique(s)

ELISA: suitable

Application

tBuBrettPhos Pd G6 bromide is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.

Learn more about G6 Buchwald precatalysts

related product

Product No.
Description
Pricing

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable


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    Bryan T Ingoglia et al.
    Organic letters, 19(11), 2853-2856 (2017-05-13)
    In this report, we describe the application of palladium-based oxidative addition complexes (OACs) as effective precatalysts for C-N, C-O, and C-F cross-coupling reactions with a variety of (hetero)arenes. These complexes offer a convenient alternative to previously developed classes of precatalysts

    Articles

    Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

    Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

    Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

    Buchwald G6 precatalysts are oxidative addition complexes that are thermally, air, and moisture stable. The catalyst activation doesn’t require a base and generates innocuous byproducts.

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