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751626

Sigma-Aldrich

Poly(ethylene glycol) methyl ether (4-cyano-4-pentanoate dodecyl trithiocarbonate)

average Mn 5,400

Synonym(s):

Dodecyl-trithiocarbonate-cyano PEG, PEG-RAFT, Poly(ethylene glycol)methyl ether 4-cyano-4-[(dodecylsulfanylthiocarbonyl)sulfanyl]pentanoate

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About This Item

UNSPSC Code:
12352100
NACRES:
NA.23

form

solid

Quality Level

mol wt

average Mn 5,400

transition temp

Tm 55-60 °C

PDI

≤1.1

Ω-end

4-cyano-4-pentanoate dodecyl trithiocarbonate

α-end

methoxy

storage temp.

2-8°C

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General description

Need help choosing the correct RAFT Agent? Please consult the RAFT Agent to Monomer compatibility table.

Application

RAFT agent for controlled radical polymerization; especially suited for the polymerization of styrene, acrylate, and acrylamide monomers to make lithographically and biologically important PEG-block copolymers. Chain Transfer Agent (CTA)

Storage Class Code

11 - Combustible Solids

WGK

WGK 3


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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)

Articles

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

Reversible addition–fragmentation chain transfer (RAFT) polymerization is rapidly moving to the forefront in construction of drug and gene delivery vehicles.

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