62421
Lithium aluminum hydride
≥97.0% (gas-volumetric), tablet (5 g each)
Synonym(s):
LAH, Lithium alanate, Lithium tetrahydroaluminate
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About This Item
Linear Formula:
LiAlH4
CAS Number:
Molecular Weight:
37.95
EC Number:
MDL number:
UNSPSC Code:
26111700
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥97.0% (gas-volumetric)
form
tablet (5 g each)
reaction suitability
reagent type: reductant
mp
125 °C (dec.) (lit.)
SMILES string
[Li].[AlH3]
InChI
1S/Al.Li.4H/q-1;+1;;;;
InChI key
OCZDCIYGECBNKL-UHFFFAOYSA-N
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Other Notes
Review
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1A - Water-react 1
Storage Class Code
4.3 - Hazardous materials which set free flammable gases upon contact with water
WGK
WGK 1
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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H.C. Brown et al.
Tetrahedron, 35, 567-567 (1979)
I-Chi Lee et al.
Organic & biomolecular chemistry, 9(22), 7655-7658 (2011-09-17)
Specific deuterated reference compounds were prepared to probe the stereoselectivity of the reductive ring opening of carbohydrate-based benzylidene-type acetals. AlD(3) revealed a retentive stereoselectivity probably through the rare S(N)i (internal nucleophilic substitution) mechanism. An S(N)1-like mechanism occurs in the acid-promoted
Seiji Takeda et al.
Journal of biomedical nanotechnology, 9(2), 303-306 (2013-05-01)
Measurement of oxidized low-density lipoprotein (LDL) generated by oxidative stress of various kinds might be useful for evaluating the risk of cardiovascular disease. We evaluated some electrode materials to detect oxidized LDL electrochemically. Some carbon nanotube dispersions were studied as
Pseudo-allosteric recognition of mandelic acid with an enantioselective coordination complex.
Jungseok Heo et al.
Angewandte Chemie (International ed. in English), 45(6), 941-944 (2005-12-31)
Matthias D'hooghe et al.
Organic & biomolecular chemistry, 8(3), 607-615 (2010-01-22)
trans- and cis-1-Alkyl-4-aryl-3-chloroazetidin-2-ones, prepared through cyclocondensation of chloroketene and the appropriate imines in a diastereoselective way, were transformed into the corresponding non-activated trans- and cis-2-aryl-3-(hydroxymethyl)aziridines via reductive ring contraction using LiAlH(4) in Et(2)O. Furthermore, trans-2-aryl-3-(hydroxymethyl)aziridines were transformed into 2-amino-3-arylpropan-1-ols and
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