409049
(1,5-Cyclooctadiene)dimethylplatinum(II)
97%
Synonym(s):
Dimethyl(cyclooctadiene)platinum, Pt(cod)(Me)2
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About This Item
Empirical Formula (Hill Notation):
C10H18Pt
CAS Number:
Molecular Weight:
333.33
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
97%
reaction suitability
core: platinum
reagent type: catalyst
mp
103-105 °C (lit.)
SMILES string
C[Pt]C.C1CC=CCCC=C1
InChI
1S/C8H12.2CH3.Pt/c1-2-4-6-8-7-5-3-1;;;/h1-2,7-8H,3-6H2;2*1H3;/b2-1-,8-7-;;;
InChI key
ZABVBYGUHBRHFJ-PHFPKPIQSA-N
General description
(1,5-Cyclooctadiene)dimethylplatinum (II) is a coordination compound in which platinum (Pt) is surrounded by two methyl (CH3) groups and one 1,5-cyclooctadiene (COD) group. It is often used as a precursor in the synthesis of platinum catalysts, which have a wide range of applications in different organic reactions.
Application
(1,5-Cyclooctadiene)dimethylplatinum(II) can be used as a platinum precursor in the preparation of:
- Hydrophobic platinum catalyst in the presence of reducing agent (NaBH4).
- Pt/Hβ catalysts for the selective isomerization of n-butane to isobutane.
Signal Word
Warning
Hazard Statements
Precautionary Statements
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
Target Organs
Respiratory system
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Preparation of hydrophobic platinum catalysts using a water-in-CO2 microemulsion
Shimizu R, et al.
Journal of Supercritical Fluids, 44(1), 109-114 (2008)
The room temperature substitution of n-and iso-perfluoropropyl iodides and n-perfluorobutyl iodide to dimethylplatinum (II) 1, 5-cyclooctadiene: The crystal structure of [Pt (C3F7) 2 (COD)]
Thomson J, et al.
Inorganic Chemistry Communications, 8(9), 782-784 (2005)
The controlled synthesis of Pt/H? catalysts with intimate metal-acid sites for n-butane isomerization
Wang P, et al.
Microporous and Mesoporous Materials : The Official Journal of the International Zeolite Association, 309, 110547-110547 (2020)
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