403547

3,6-Di-2-pyridyl-1,2,4,5-tetrazine

96%

• Empirical Formula (Hill Notation): C₁₂H₈N₆
• CAS Number: 1671-87-0
• Molecular Weight: 236.23
• MDL number: MFCD00121717
• UNSPSC Code: 12352100
• PubChem Substance ID: 24865200
• NACRES: NA.22

Properties

• Quality Level: 100
• Assay: 96%
• form: solid
• mp: 225 °C (dec.) (lit.)
• SMILES string: c1ccc(nc1)-c2nnc(nn2)-c3ccccn3
• InChI: 1S/C12H8N6/c1-3-7-13-9(5-1)11-15-17-12(18-16-11)10-6-2-4-8-14-10/h1-8H
• InChI key: JFBIRMIEJBPDTQ-UHFFFAOYSA-N

Description

General description

3,6-Di-2-pyridyl-1,2,4,5-tetrazine (DPTZ) undergoes solvothermal reaction with CuSO₄.6H₂O and Cu(Ac)₂.H₂O to afford copper containing coordination polymers. It reacts with enamine derivative of morpholine and 5-,6-,7- and 8-membered cyclic ketones to afford pyridazine derivatives.

3,6-Di-2-pyridyl-1,2,4,5-tetrazine undergoes solid-state reaction with fullerene C₆₀ by high-speed vibration milling technique. It acts as electron-deficient diene in the inverse electron demand Diels Alder reaction.

Application

3,6-Di-2-pyridyl-1,2,4,5-tetrazine may be used in the following studies:

• Preparation of mononuclear, cyclic tetranuclear, and 1-D helical-chain Cu(II) complexes, via metal-assisted hydrolysis.
• Synthesis of novel cyclic tetranuclear Zn^II complex.
• Synthesis of substituted 3,6-di(2-pyridyl)pyridazines, via inverse electron demand Diels Alder reaction with alkenes or alkynes.

Safety Information

• Pictograms: GHS07
• Signal Word: Warning
• Hazard Statements: H315,H319,H335
• Precautionary Statements: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• Hazard Classifications: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• Target Organs: Respiratory system
• Storage Class Code: 11 - Combustible Solids
• WGK: WGK 3
• Flash Point(F): Not applicable
• Flash Point(C): Not applicable
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves