332828

2-Butanone oxime

99%

• Synonym(s): Methyl ethyl ketoxime
• Linear Formula: C₂H₅C(=NOH)CH₃
• CAS Number: 96-29-7
• Molecular Weight: 87.12
• Beilstein: 1698241
• EC Number: 202-496-6
• MDL number: MFCD00013935
• UNSPSC Code: 12352100
• PubChem Substance ID: 24860083
• NACRES: NA.22

Properties

• vapor density: 3 (vs air)
• vapor pressure: <8 mmHg ( 20 °C)
• Assay: 99%
• form: liquid
• refractive index: n20/D 1.442 (lit.)
• bp: 59-60 °C/15 mmHg (lit.)
• solubility: water: soluble 100 g/L at 25 °C
• density: 0.924 g/mL at 25 °C (lit.)
• functional group: amine; oxime
• SMILES string: CC\C(C)=N\O
• InChI: 1S/C4H9NO/c1-3-4(2)5-6/h6H,3H2,1-2H3/b5-4+
• InChI key: WHIVNJATOVLWBW-SNAWJCMRSA-N

Description

General description

2-Butanone oxime is an antioxidant and blocking agent used in the synthesis of water-dispersible blocked polyurethane.

Application

2-Butanone oxime was employed as reagent and solvent in the syntheses of ketoimine and 2,4-dipyridyl-1,3,5-triazapentadiene palladium(II) complexes. It was also used in the synthesis of novel acetaldiimine cobalt complex, [CoI₂{((CH₃CH₂)(CH₃)C=NO)₂C(CH₃)₂}].

Safety Information

• Pictograms: GHS06,GHS08,GHS05
• Signal Word: Danger
• Hazard Statements: H301,H312,H315,H317,H318,H336,H350,H370,H373
• Precautionary Statements: P202 - P260 - P280 - P301 + P310 - P302 + P352 + P312 - P305 + P351 + P338
• Hazard Classifications: Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Carc. 1B - Eye Dam. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 2 - STOT SE 1 - STOT SE 3
• Target Organs: Blood, Central nervous system, Upper respiratory tract
• Storage Class Code: 6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
• WGK: WGK 3
• Flash Point(F): 143.5 °F - closed cup
• Flash Point(C): 61.97 °C - closed cup
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves