Skip to Content
Merck
All Photos(1)

Key Documents

189979

Sigma-Aldrich

N,N-Dimethylformamide-d7

≥99.5 atom % D

Synonym(s):

DMF-d7, Heptadeutero-N,N-dimethylformamide

Sign Into View Organizational & Contract Pricing


About This Item

Linear Formula:
DCON(CD3)2
CAS Number:
Molecular Weight:
80.14
Beilstein:
1908468
MDL number:
UNSPSC Code:
12142201
PubChem Substance ID:
NACRES:
NA.21

Pricing and availability is not currently available.

isotopic purity

≥99.5 atom % D

Quality Level

Assay

≥99% (CP)

form

liquid

technique(s)

NMR: suitable

impurities

≤0.05% water
water

refractive index

n20/D 1.428 (lit.)

bp

153 °C (lit.)

density

1.03 g/mL at 25 °C (lit.)

mass shift

M+7

Looking for similar products? Visit Product Comparison Guide

Compare Similar Items

View Full Comparison

Show Differences

1 of 4

This Item
AXYVT38470ULRSAXYVT3845ULRAXYVT38470ULR
sterility

sterile

sterility

sterile

sterility

-

sterility

-

packaging

pkg of 5x3840tips/cs

packaging

pkg of 5x3840tips/cs

packaging

pkg of 5x3840tips/cs

packaging

pkg of 5x3840tips/cs

size

10 μL

size

70 μL

size

5 μL

size

70 μL

General description

N,N-Dimethylformamide-d7 (DMF-d7) is a deuterated derivative of N,N-dimethylformamide. It has an isotopic purity of 99.5atom%D. It is a standard purity solvent suitable for routine NMR analyses (conducted at ambient temperatures where quality is less critical). It participates as a solvent to evaluate the solvation of 1.7molar solution of lithium chloride (LiCl) by pulsed neutron diffraction studies.[1] Quadrupole splittings and quadrupole coupling constants of DMF-d7 oriented in a nematic phase have been evaluated by deuteron magnetic resonance studies.[2] DMF-d7 is being considered as a potent anti-cancer drug.[3]

Application

N,N-Dimethylformamide-d7 may be used to study its metabolism in rats by 2H NMR spectroscopy.[4]

Recommended products

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

Signal Word

Danger

Hazard Classifications

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 2

Flash Point(F)

135.5 °F - closed cup

Flash Point(C)

57.5 °C - closed cup


Choose from one of the most recent versions:

Certificates of Analysis (COA)

Lot/Batch Number

Don't see the Right Version?

If you require a particular version, you can look up a specific certificate by the Lot or Batch number.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Deuterium NMR spectroscopy of biofluids for the identification of drug metabolites: application to N, N-dimethylformamide.
Farrant RD, et al.
Journal of Pharmaceutical and Biomedical Analysis, 11(8), 687-692 (1993)
Investigation of the feasibility of directly-coupled HPLC-NMR with 2H detection with application to the metabolism of N-dimethylformamide-d7.
Farrant RD, et al.
Journal of Pharmaceutical and Biomedical Analysis, 16(1), 1-5 (1997)
NMR determination of quadrupole coupling constants of deuterons in N, N-dimethylformamide-d7.
Balakrishnan NS.
Journal of Magnetic Resonance, 83(2), 233-245 (1989)
Neutron diffraction study on chloride ion solvation in water, methanol, and N,N-dimethylformamide.
Yamagami M, et al.
J. Chem. Phys. , 103(18), 8174-8178 (1995)
Małgorzata Fabijańska et al.
Dalton transactions (Cambridge, England : 2003), 44(3), 938-947 (2014-08-12)
This paper describes the synthesis of trans-bis-(3-aminoflavone)dichloridoplatinum(ii) (trans-Pt(3-af)2Cl2; TCAP) for use as a potential anticancer compound, and the evaluation of its structure by elemental and spectral analyses, and X-ray crystallography. The complex demonstrated a significant cytotoxic effect against human and

Articles

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Use this reference table to find the coupling values and chemical shifts of our NMR (deuterated) solvents. Melting and boiling points, molecular weight, density, and CAS number are also listed.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service