63405
Methyl potassium malonate
≥99.0% (NT)
Synonym(s):
Monomethyl malonate potassium salt, Potassium monomethyl malonate
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About This Item
Linear Formula:
CH3OCOCH2COOK
CAS Number:
Molecular Weight:
156.18
Beilstein:
3633585
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
Assay
≥99.0% (NT)
functional group
ester
SMILES string
[K+].COC(=O)CC([O-])=O
InChI
1S/C4H6O4.K/c1-8-4(7)2-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
InChI key
WWTULTKUWBKVGV-UHFFFAOYSA-M
Application
Methyl potassium malonate can be used in the total synthesis of (±)-vincorine, an akuammiline alkaloid which can find applications in biology. It can also be used to synthesize a key keto proline ester intermediate to prepare acutumine.
Storage Class Code
11 - Combustible Solids
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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