359297
Sodium ethanethiolate
technical grade, 80%
Synonym(s):
Ethanethiol sodium salt, Ethyl mercaptan sodium salt
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About This Item
Linear Formula:
CH3CH2SNa
CAS Number:
Molecular Weight:
84.12
Beilstein:
3593647
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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grade
technical grade
Quality Level
Assay
80%
SMILES string
CCS[Na]
InChI
1S/C2H6S.Na/c1-2-3;/h3H,2H2,1H3;/q;+1/p-1
InChI key
QJDUDPQVDAASMV-UHFFFAOYSA-M
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General description
Reaction of FeCl2 or FeCl3 with sodium ethanethiolate in N-methylformamide (NMF) has been evaluated. Reaction of sodium ethanethiolate with substituted 1,2-dithiole-3-thiones has been studied.
Application
Sodium ethanethiolate may be used in the equilibrium titrations in N-methylformamide of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase. It may be used in the synthesis of a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine.
Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Skin Corr. 1B
Supplementary Hazards
Storage Class Code
8A - Combustible corrosive hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Personal Protective Equipment
dust mask type N95 (US), Eyeshields, Gloves
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Reactivity of substituted 1, 2-dithiole-3-thiones with sodium ethanethiolate: a convenient route to a novel heterocycle.
Largeron M, et al.
Tetrahedron, 43(15), 3421-3428 (1987)
Patrick Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 10(4), 373-382 (2005-05-03)
The reaction of FeCl(2) or FeCl(3) with sodium ethanethiolate (SEt) in N-methylformamide (NMF) has been reevaluated to rectify a previous Fe(II) oxidation artifact. On titrating Fe(II) with EtS(-) concentrations up to 12 mol Eq, new features in the UV/vis spectrum
P Frank et al.
Journal of biological inorganic chemistry : JBIC : a publication of the Society of Biological Inorganic Chemistry, 6(7), 683-697 (2001-10-30)
Equilibrium titrations in N-methylformamide (NMF) of G-25 gel filtered (ox)-state FeMo cofactor [FeMoco(ox)] from Azotobacter vinelandii nitrogenase were carried out using sodium ethanethiolate and followed using UV/Vis absorption spectroscopy. For Fe-Moco(ox), a non-linear least squares (NLLSQ) fit to the data
Maria Koufaki et al.
Bioorganic & medicinal chemistry, 11(23), 5209-5219 (2003-11-08)
We have synthesized a series of hybrid compounds combining the pharmacophoric redox moieties of vitamin E and key features responsible for the antiarrhythmic properties of the class I antiarrhythmics procainamide and lidocaine. Procainamide analogue (2a) and lidocaine analogues (14a) and
Pinar Kasaplar et al.
Bioorganic chemistry, 38(5), 186-189 (2010-07-27)
The mechanism of action for alpha,beta-unsaturated lactones can be explained by their Michael acceptor properties. They have the potential of being covalently binding inhibitors by accepting nucleophiles from target proteins. In this work, Michael addition reactions of ethanethiol with 6-bicycloaryl
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