If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf
1.00456
Nitric acid
65%, for analysis EMSURE® Reag. Ph Eur,ISO
Synonym(s):
Nitric acid solution
About This Item
reag. Ph. Eur.
Recommended Products
Product Name
Nitric acid 65%, for analysis EMSURE® Reag. Ph Eur,ISO
Agency
reag. ISO
reag. Ph. Eur.
Quality Level
vapor pressure
9.4 hPa ( 20 °C)
product line
EMSURE®
Assay
≥65.0% (alkalimetric)
form
liquid
impurities
≤0.010 ppm Ag (Silver)
≤0.010 ppm As (Arsenic)
≤0.010 ppm Ba (Barium)
≤0.010 ppm Be (Beryllium)
≤0.010 ppm Cd (Cadmium)
≤0.010 ppm Co (Cobalt)
≤0.010 ppm Cu (Copper)
≤0.010 ppm Li (Lithium)
≤0.010 ppm Mn (Manganese)
≤0.010 ppm Mo (Molybdenum)
≤0.010 ppm Pb (Lead)
≤0.010 ppm Sr (Strontium)
≤0.010 ppm V (Vanadium)
≤0.020 ppm Bi (Bismuth)
≤0.020 ppm Cr (Chromium)
≤0.020 ppm Ge (Germanium)
≤0.020 ppm In (Indium)
≤0.020 ppm Ni (Nickel)
≤0.020 ppm Ti (Titanium)
≤0.020 ppm Tl (Thallium)
≤0.020 ppm Zn (Zinc)
≤0.020 ppm Zr (Zirconium)
≤0.050 ppm Al (Aluminium)
≤0.050 ppm Au (Gold)
≤0.050 ppm Ga (Gallium)
≤0.050 ppm Mg (Magnesium)
≤0.100 ppm Ca (Calcium)
≤0.100 ppm Fe (Iron)
≤0.100 ppm K (Potassium)
≤0.100 ppm Pt (Platinum)
≤0.2 ppm Chloride (Cl)
≤0.2 ppm Heavy metals (as Pb)
≤0.2 ppm Phosphate (PO4)
≤0.200 ppm Na (Sodium)
≤0.5 ppm Sulfate (SO4)
SMILES string
O[N+]([O-])=O
ign. residue
≤3 ppm (as SO4)
color
APHA: ≤10
pH
<1 (20 °C in H2O, strongly acid)
bp
121 °C/1013 hPa
mp
-32 °C
density
1.39 g/cm3 at 20 °C
storage temp.
2-30°C
InChI
1S/HNO3/c2-1(3)4/h(H,2,3,4)
InChI key
GRYLNZFGIOXLOG-UHFFFAOYSA-N
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Application
- Comparison of essential and toxic elements in esophagus, lung, mouth and urinary bladder male cancer patients with related to controls.: The research utilized 65% nitric acid in the sample digestion process for the determination of trace elements in cancer patient tissues using atomic absorption spectrometry (Kazi et al., 2015).
- Interaction between carcinogenic and anti-carcinogenic trace elements in the scalp hair samples of different types of Pakistani female cancer patients.: This study employed 65% nitric acid for the digestion of scalp hair samples, analyzing trace elements through atomic absorption spectrometry (Wadhwa et al., 2015).
Analysis Note
Identity: passes test
Appearance: passes test
Color (Hazen): ≤ 10 Hazen
Density (d 20/20): 1.384 - 1.416
Chloride (Cl): ≤ 0.2 ppm
Phosphate (PO₄): ≤ 0.2 ppm
Sulfate (SO₄): ≤ 0.5 ppm
Heavy metals (as Pb): ≤ 0.2 ppm
Ag (Silver): ≤ 0.010 ppm
Al (Aluminium): ≤ 0.050 ppm
As (Arsenic): ≤ 0.010 ppm
Au (Gold): ≤ 0.050 ppm
Ba (Barium): ≤ 0.010 ppm
Be (Beryllium): ≤ 0.010 ppm
Bi (Bismuth): ≤ 0.020 ppm
Ca (Calcium): ≤ 0.100 ppm
Cd (Cadmium): ≤ 0.010 ppm
Co (Cobalt): ≤ 0.010 ppm
Cr (Chromium): ≤ 0.020 ppm
Cu (Copper): ≤ 0.010 ppm
Fe (Iron): ≤ 0.100 ppm
Ga (Gallium): ≤ 0.050 ppm
Ge (Germanium): ≤ 0.020 ppm
In (Indium): ≤ 0.020 ppm
K (Potassium): ≤ 0.100 ppm
Li (Lithium): ≤ 0.010 ppm
Mg (Magnesium): ≤ 0.050 ppm
Mn (Manganese): ≤ 0.010 ppm
Mo (Molybdenum): ≤ 0.010 ppm
Na (Sodium): ≤ 0.200 ppm
Ni (Nickel): ≤ 0.020 ppm
Pb (Lead): ≤ 0.010 ppm
Pt (Platinum): ≤ 0.100 ppm
Sr (Strontium): ≤ 0.010 ppm
Ti (Titanium): ≤ 0.020 ppm
Tl (Thallium): ≤ 0.020 ppm
V (Vanadium): ≤ 0.010 ppm
Zn (Zinc): ≤ 0.020 ppm
Zr (Zirconium): ≤ 0.020 ppm
Residue on ignition (as SO₄): ≤ 3 ppm
Date of expiry: see product label
ISO-reagent
Legal Information
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Signal Word
Danger
Hazard Statements
Precautionary Statements
Hazard Classifications
Acute Tox. 3 Inhalation - Eye Dam. 1 - Met. Corr. 1 - Ox. Liq. 3 - Skin Corr. 1A
Supplementary Hazards
Storage Class Code
5.1B - Oxidizing hazardous materials
WGK
WGK 3
Flash Point(F)
Not applicable
Flash Point(C)
Not applicable
Certificates of Analysis (COA)
Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.
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Related Content
Glass bottles are ideal for storing acids because they are inert and offer a long shelf life.
Glass bottles are ideal for storing acids because they are inert and offer a long shelf life.
Glass bottles are ideal for storing acids because they are inert and offer a long shelf life.
Glass bottles are ideal for storing acids because they are inert and offer a long shelf life.
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How can I determine the shelf life / expiration / retest date of this product?
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How is shipping temperature determined? And how is it related to the product storage temperature?
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Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf
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Warum werden zu diesem Produkt Gehaltsangaben in % oder ppm gemacht, ohne den Bezug dieser Quotienten (Masse, Volumen, ...) anzugeben? IUPAC, ISO, BIPM raten von solchen Angaben ab. Warum nicht eindeutig als Massenanteil oder Massenkonzentration benennen?
1 answer-
These content or product details are reported as such for practical purposes. All of the units reported for this product can be used directly in calculations related to product usage.
For example, the nitric acid is 65% by assay of a 1 Liter bottle. It means that 650 mL equals nitric acid. The literature density of Nitric acid is 1.51g/mL. Thus the mass of nitric acid in that bottle is 1.51g/mL * 650mL = 981.5g
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