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E14551

Sigma-Aldrich

Ethyl 2-bromopropionate

99%

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About This Item

Linear Formula:
CH3CHBrCOOC2H5
CAS Number:
535-11-5
Molecular Weight:
181.03
Beilstein:
773920
EC Number:
208-609-5
MDL number:
MFCD00000144
UNSPSC Code:
12352100
PubChem Substance ID:
24894411
NACRES:
NA.22

Assay

99%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

156-160 °C (lit.)

density

1.394 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(C)Br

InChI

1S/C5H9BrO2/c1-3-8-5(7)4(2)6/h4H,3H2,1-2H3

InChI key

ARFLASKVLJTEJD-UHFFFAOYSA-N

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Related Categories

Pictograms

FlameCorrosion
GHS02,GHS05

Signal Word

Danger

Hazard Statements

H226,H314

Hazard Classifications

Flam. Liq. 3 - Skin Corr. 1B

Storage Class Code

3 - Flammable liquids

WGK

WGK 3

Flash Point(F)

123.8 °F - closed cup

Flash Point(C)

51 °C - closed cup

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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A straightforward transformation protocol combining two distinct living polymerization methods for the controlled synthesis of block copolymers is described. In the first step, bromo-terminated poly(methyl methacrylate) is prepared by atom transfer radical polymerization (ATRP). Then, a bromide end group is
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NIR exposure at 790 nm activated photopolymerization of monomers comprising UV-absorbing moieties by using [CuII /(TPMA)]Br2 (TPMA=tris(2-pyridylmethyl)amine) in the ppm range and an alkyl bromide as initiator. Some of them comprised structural elements selected either from those showing proton transfer or
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